Catalyst recycling via hydrogen-bonding-based affinity tags

B.W.T. Gruijters; M.A.C. Broeren; F.L. Delft, van; R.P. Sijbesma; P.H.H. Hermkens; F.P.J.T. Rutjes

doi:10.1021/ol0607387

Catalyst recycling via hydrogen-bonding-based affinity tags

B.W.T. Gruijters
, M.A.C. Broeren
, F.L. Delft, van
, R.P. Sijbesma
, P.H.H. Hermkens
, F.P.J.T. Rutjes

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

45 Citaten (Scopus)

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A novel procedure for catalyst recycling is described. Copper(I)-based catalysts, equipped with an affinity tag, are isolated from crude reaction mixtures on the basis of quadruple hydrogen-bonding interactions using a resin functionalized with complementary affinity tags. Recycled catalysts were successfully used to catalyze a tandem Sonogashira coupling/5-endo-dig cyclization and a Cu-catalyzed [3+2] Huisgen cycloaddition reaction in high yields.

Originele taal-2	Engels
Pagina's (van-tot)	3163-3166
Aantal pagina's	4
Tijdschrift	Organic Letters
Volume	8
Nummer van het tijdschrift	15
DOI's	https://doi.org/10.1021/ol0607387
Status	Gepubliceerd - 2006

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10.1021/ol0607387

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title = "Catalyst recycling via hydrogen-bonding-based affinity tags",

abstract = "A novel procedure for catalyst recycling is described. Copper(I)-based catalysts, equipped with an affinity tag, are isolated from crude reaction mixtures on the basis of quadruple hydrogen-bonding interactions using a resin functionalized with complementary affinity tags. Recycled catalysts were successfully used to catalyze a tandem Sonogashira coupling/5-endo-dig cyclization and a Cu-catalyzed [3+2] Huisgen cycloaddition reaction in high yields.",

author = "B.W.T. Gruijters and M.A.C. Broeren and \{Delft, van\}, F.L. and R.P. Sijbesma and P.H.H. Hermkens and F.P.J.T. Rutjes",

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AU - Gruijters, B.W.T.

AU - Broeren, M.A.C.

AU - Delft, van, F.L.

AU - Sijbesma, R.P.

AU - Hermkens, P.H.H.

AU - Rutjes, F.P.J.T.

PY - 2006

Y1 - 2006

N2 - A novel procedure for catalyst recycling is described. Copper(I)-based catalysts, equipped with an affinity tag, are isolated from crude reaction mixtures on the basis of quadruple hydrogen-bonding interactions using a resin functionalized with complementary affinity tags. Recycled catalysts were successfully used to catalyze a tandem Sonogashira coupling/5-endo-dig cyclization and a Cu-catalyzed [3+2] Huisgen cycloaddition reaction in high yields.

AB - A novel procedure for catalyst recycling is described. Copper(I)-based catalysts, equipped with an affinity tag, are isolated from crude reaction mixtures on the basis of quadruple hydrogen-bonding interactions using a resin functionalized with complementary affinity tags. Recycled catalysts were successfully used to catalyze a tandem Sonogashira coupling/5-endo-dig cyclization and a Cu-catalyzed [3+2] Huisgen cycloaddition reaction in high yields.

U2 - 10.1021/ol0607387

DO - 10.1021/ol0607387

M3 - Article

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SP - 3163

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JO - Organic Letters

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Catalyst recycling via hydrogen-bonding-based affinity tags

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