@inproceedings{085f4ccec05f4801b9ecb90ad1b50ae4,
title = "Catalyst deactivation and reactivation during aqueous alcohol oxidation in a redox-cycle reactor",
abstract = "Platinum catalyst deactivation during aqueous alcohol oxidation is discussed, using the oxidation of methyl -D-glucopyranoside as an example. The most important causes of platinum deactivation are catalyst over-oxidation and catalyst poisoning. Deactivation by over-oxidation can be reversed by applying a redox-cycle, i.e. cyclic exposure to oxidative and reductive circumstances. A kinetic model for methyl -D-glycopyranoside oxidation, platinum deactivation, and reactivation is presented and implemented into a three-phase stirred slurry reactor model, clearly showing the advantages of redox-cycles.",
author = "A.P. Markusse and B.F.M. Kuster and J.C. Schouten",
year = "1999",
doi = "10.1016/S0167-2991(99)80476-5",
language = "English",
isbn = "9780444502131",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier",
pages = "273--280",
editor = "B. Delmon and G.F. Froment",
booktitle = "Catalyst deactivation 1999 : proceedings of the 8th International Symposium, Brugge, Belgium, October 10-13, 1999",
address = "Netherlands",
note = "conference; International Symposium on Catalys Deactivation ; 8 (Brugge, Belgium) : 1999.10.10-13; 1999-10-10; 1999-10-13 ; Conference date: 10-10-1999 Through 13-10-1999",
}