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Analytical ultracentrifugation studies on terpyridine-end-functionalized poly(ethylene oxide) and polystyrene systems complexed via Ru(II) ions

  • M.V Rasa
  • , C. Tziatzios
  • , B.G.G. Lohmeijer
  • , D. Schubert
  • , U.S. Schubert

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

Samenvatting

In this paper we study the solution properties of several metallo-supramolecular assemblies containing polystyrene (PS) and poly(ethylene oxide) (PEO) blocks linked via Ru2+ ions: PS20–[Ru2+]–PEO70, PS20–[Ru2+]–PS20, and PEO225–[Ru2+]–PEO225. Sedimentation equilibrium measurements were performed to determine the molar mass distribution and state of association, and the sedimentation velocity measurements were used to obtain the molar mass distribution, sedimentation coefficient distribution, their average values, and average diffusion coefficient. The results obtained from the two types of experiments are compared and discussed. Association - Analytical ultracentrifugation - Assemblies - Metallo-supramolecular - Molar mass - Sedimentation
Originele taal-2Engels
TitelAnalytical ultracentrifugation VIII
Subtitel14th International Symposium on Analytical Ultracentrifugation, Lausanne, Switzerland, March 1 - 2, 2005
RedacteurenC. Wandrey, H. Cölfen
Plaats van productieBerlin
UitgeverijSpringer
Hoofdstuk15
Pagina's165-171
Aantal pagina's7
ISBN van elektronische versie978-3-540-34279-3
ISBN van geprinte versie978-3-540-29615-7
DOI's
StatusGepubliceerd - 2006
Evenementconference; International Symposium on Analytical Ultracentrifugation ; 14 (Lausanne, Switzerland) : 2005.03.01-02 -
Duur: 1 jan. 2006 → …

Publicatie series

NaamProgress in Colloid and Polymer Science (PROGCOLLOID)
Volume131
ISSN van geprinte versie0340-255X

Congres

Congresconference; International Symposium on Analytical Ultracentrifugation ; 14 (Lausanne, Switzerland) : 2005.03.01-02
Periode1/01/06 → …
AnderInternational Symposium on Analytical Ultracentrifugation ; 14 (Lausanne, Switzerland) : 2005.03.01-02

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