Amphiphilic Statistical Copolymers from Catalytic Chain Transfer as Reactive Surfactants in Emulsion Polymerization

Ingeborg Schreur-Piet; Johan P.A. Heuts

doi:10.1021/acsapm.1c00715

Amphiphilic Statistical Copolymers from Catalytic Chain Transfer as Reactive Surfactants in Emulsion Polymerization

Ingeborg Schreur-Piet, Johan P.A. Heuts (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Statistical copolymers of methacrylic acid (MAA) and methyl methacrylate (MMA), butyl methacrylate (BMA), or lauryl methacrylate (LMA) were synthesized via cobalt(II)-mediated catalytic chain transfer polymerization (CCTP) and used as macromonomeric stabilizers in the emulsion polymerization of MMA. By varying the composition, length, and concentration of the macromonomers, we were able to tune the particle size, molar mass, and rheological behavior of the latexes. Most latexes stabilized with macromonomers containing BMA and LMA showed rheological properties such as small yield stress and shear thinning behavior similar to those of binders for coating applications.

Originele taal-2	Engels
Pagina's (van-tot)	4616–4624
Aantal pagina's	9
Tijdschrift	ACS Applied Polymer Materials
Volume	3
Nummer van het tijdschrift	9
DOI's	https://doi.org/10.1021/acsapm.1c00715
Status	Gepubliceerd - 5 aug. 2021

Bibliografische nota

Funding Information:
We gratefully acknowledge financial support by the Stichting Emulsion Polymerization. Patricia Marín is gratefully acknowledged for help with the NMR measurements. Electron microscopy was performed at the Center for Multiscale Electron Microscopy at Eindhoven University of Technology.

Publisher Copyright:
© 2021 The Authors. Published by American Chemical Society.

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10.1021/acsapm.1c00715

published versionDefinitieve gepubliceerde versie, 1,41 MBLicentie: CC BY-NC-ND

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title = "Amphiphilic Statistical Copolymers from Catalytic Chain Transfer as Reactive Surfactants in Emulsion Polymerization",

abstract = "Statistical copolymers of methacrylic acid (MAA) and methyl methacrylate (MMA), butyl methacrylate (BMA), or lauryl methacrylate (LMA) were synthesized via cobalt(II)-mediated catalytic chain transfer polymerization (CCTP) and used as macromonomeric stabilizers in the emulsion polymerization of MMA. By varying the composition, length, and concentration of the macromonomers, we were able to tune the particle size, molar mass, and rheological behavior of the latexes. Most latexes stabilized with macromonomers containing BMA and LMA showed rheological properties such as small yield stress and shear thinning behavior similar to those of binders for coating applications. ",

keywords = "catalytic chain transfer, copolymerization, emulsion polymerization, macromonomer, methacrylic acid, reactive surfactant",

author = "Ingeborg Schreur-Piet and Heuts, {Johan P.A.}",

note = "Funding Information: We gratefully acknowledge financial support by the Stichting Emulsion Polymerization. Patricia Mar{\'i}n is gratefully acknowledged for help with the NMR measurements. Electron microscopy was performed at the Center for Multiscale Electron Microscopy at Eindhoven University of Technology. Publisher Copyright: {\textcopyright} 2021 The Authors. Published by American Chemical Society.",

year = "2021",

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doi = "10.1021/acsapm.1c00715",

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AU - Schreur-Piet, Ingeborg

AU - Heuts, Johan P.A.

N1 - Funding Information: We gratefully acknowledge financial support by the Stichting Emulsion Polymerization. Patricia Marín is gratefully acknowledged for help with the NMR measurements. Electron microscopy was performed at the Center for Multiscale Electron Microscopy at Eindhoven University of Technology. Publisher Copyright: © 2021 The Authors. Published by American Chemical Society.

PY - 2021/8/5

Y1 - 2021/8/5

N2 - Statistical copolymers of methacrylic acid (MAA) and methyl methacrylate (MMA), butyl methacrylate (BMA), or lauryl methacrylate (LMA) were synthesized via cobalt(II)-mediated catalytic chain transfer polymerization (CCTP) and used as macromonomeric stabilizers in the emulsion polymerization of MMA. By varying the composition, length, and concentration of the macromonomers, we were able to tune the particle size, molar mass, and rheological behavior of the latexes. Most latexes stabilized with macromonomers containing BMA and LMA showed rheological properties such as small yield stress and shear thinning behavior similar to those of binders for coating applications.

AB - Statistical copolymers of methacrylic acid (MAA) and methyl methacrylate (MMA), butyl methacrylate (BMA), or lauryl methacrylate (LMA) were synthesized via cobalt(II)-mediated catalytic chain transfer polymerization (CCTP) and used as macromonomeric stabilizers in the emulsion polymerization of MMA. By varying the composition, length, and concentration of the macromonomers, we were able to tune the particle size, molar mass, and rheological behavior of the latexes. Most latexes stabilized with macromonomers containing BMA and LMA showed rheological properties such as small yield stress and shear thinning behavior similar to those of binders for coating applications.

KW - catalytic chain transfer

KW - copolymerization

KW - emulsion polymerization

KW - macromonomer

KW - methacrylic acid

KW - reactive surfactant

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DO - 10.1021/acsapm.1c00715

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JO - ACS Applied Polymer Materials

JF - ACS Applied Polymer Materials

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ER -

Amphiphilic Statistical Copolymers from Catalytic Chain Transfer as Reactive Surfactants in Emulsion Polymerization

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