Alternation and tunable composition in hydrogen bonded supramolecular copolymers

T.M. Felder; T.F.A. Greef, de; M.M.L. Nieuwenhuizen; R.P. Sijbesma

doi:10.1039/C3CC46611F

Alternation and tunable composition in hydrogen bonded supramolecular copolymers

T.M. Felder, T.F.A. Greef, de, M.M.L. Nieuwenhuizen, R.P. Sijbesma

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Sequence control in supramolecular copolymers is limited by the selectivity of the associating monomer end groups. Here we introduce the use of monomers with aminopyrimidinone and aminohydroxynaphthyridine quadruple hydrogen bonding end groups, which both homodimerize, but form even stronger heterodimers. These features allow the formation of supramolecular copolymers with a tunable composition and a preference for alternating sequences.

Originele taal-2	Engels
Pagina's (van-tot)	2455-2457
Aantal pagina's	3
Tijdschrift	Chemical Communications, ChemComm
Volume	50
Nummer van het tijdschrift	19
DOI's	https://doi.org/10.1039/C3CC46611F
Status	Gepubliceerd - 2014

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10.1039/C3CC46611F

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abstract = "Sequence control in supramolecular copolymers is limited by the selectivity of the associating monomer end groups. Here we introduce the use of monomers with aminopyrimidinone and aminohydroxynaphthyridine quadruple hydrogen bonding end groups, which both homodimerize, but form even stronger heterodimers. These features allow the formation of supramolecular copolymers with a tunable composition and a preference for alternating sequences.",

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AU - Sijbesma, R.P.

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AB - Sequence control in supramolecular copolymers is limited by the selectivity of the associating monomer end groups. Here we introduce the use of monomers with aminopyrimidinone and aminohydroxynaphthyridine quadruple hydrogen bonding end groups, which both homodimerize, but form even stronger heterodimers. These features allow the formation of supramolecular copolymers with a tunable composition and a preference for alternating sequences.

U2 - 10.1039/C3CC46611F

DO - 10.1039/C3CC46611F

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Alternation and tunable composition in hydrogen bonded supramolecular copolymers

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