Adiabatic electrochemical electron-transfer reactions involving frequency changes of inner-sphere modes

W. Schmickler, M.T.M. Koper

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

16 Citaten (Scopus)

Samenvatting

A Hamiltonian model is formulated for electrochemical electron-transfer reactions involving frequency changes of the inner-sphere modes. The adiabatic free energy surface is calculated and it is shown that this nonlinear coupling leads to a transfer coefficient different from , and that the transfer coefficient can no longer be identified with the electron occupation probability in the transition state saddle point, as in the linear coupling case.
Originele taal-2Engels
Pagina's (van-tot)402-405
TijdschriftElectrochemistry Communications
Volume1
Nummer van het tijdschrift9
DOI's
StatusGepubliceerd - 1999

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