A unified view on nanoscale packing, connectivity, and conductivity of CNT networks

Karthikeyan Gnanasekaran, Claudio Grimaldi, Gijsbertus de With, Heiner Friedrich (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

4 Citaten (Scopus)
12 Downloads (Pure)

Samenvatting

The design of functional structures from primary building blocks requires a thorough understanding of how size, shape, and particle–particle interactions steer the assembly process. Specifically, for electrically conductive networks build from carbon nanotubes (CNTs) combining macroscopic characterization and simulations shows that the achievable conductivity is mainly governed by CNT aspect ratio, length dispersity and attractive interactions. However, a direct link between the actual 3D network topology that leads to the observed electrical conductivity has not been established yet due to a lack in nanoscale experimental approaches. Here it is shown experimentally for randomly packed (jammed) CNT networks that the CNT aspect ratio determines, as theoretically predicted, the contact number per CNT which in turn scales linearly with the resulting electrical conductivity of the CNT network. Furthermore, nanoscale packing density, contact areas, contact distribution in random and nonrandom configurations, and least resistance pathways are quantified. The results illustrate how complex nanoscale networks can be imaged and quantified in 3D to understand and model their functional properties in a bottom-up fashion.

Originele taal-2Engels
Artikelnummer1807901
Aantal pagina's6
TijdschriftAdvanced Functional Materials
Volume29
Nummer van het tijdschrift13
Vroegere onlinedatum1 jan 2019
DOI's
StatusGepubliceerd - 28 mrt 2019

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  • Uitrusting

    Center for Multiscale Electron Microscopy (CMEM)

    Heiner Friedrich (Manager), Rick Joosten (Gebruiker), Demi de Moor (Gebruiker), Pauline Schmit (Gebruiker), Ingeborg Schreur - Piet (Gebruiker), Anne Spoelstra (Gebruiker) & Nina Romme - van Moll (Inhoud)

    Materials and Interface Chemistry

    Uitrusting/faciliteit: Onderzoekslaboratorium

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