A supramolecular strategy based on molecular dipole moments for high-quality covalent organic frameworks

Laura M. Salonen, Dana D. Medina, Enrique Carbó-Argibay, Maarten G. Goesten, Luís Mafra, Noelia Guldris, Julian M. Rotter, Daniel G. Stroppa, Carlos Rodríguez-Abreu

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

26 Citaten (Scopus)

Samenvatting

A supramolecular strategy based on strong molecular dipole moments is presented to gain access to covalent organic framework structures with high crystallinity and porosity. Antiparallel alignment of the molecules within the pore walls is proposed to lead to reinforced columnar stacking, thus affording a high-quality material. As a proof of principle, a novel pyrene dione building block was prepared and reacted with hexahydroxytriphenylene to form a boronic ester-linked covalent organic framework. We anticipate the strategy presented herein to be valuable for producing highly defined COF structures.

Originele taal-2Engels
Pagina's (van-tot)7986-7989
Aantal pagina's4
TijdschriftChemical Communications
Volume52
DOI's
StatusGepubliceerd - 1 jan 2016

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