A Mössbauer study of Al and Ga substituted magnetite

M. Rosenberg; P. Deppe; H.U. Janssen; V.A.M. Brabers; F.S. Li; S. Dey

doi:10.1063/1.334954

A Mössbauer study of Al and Ga substituted magnetite

M. Rosenberg, P. Deppe, H.U. Janssen, V.A.M. Brabers, F.S. Li, S. Dey

Physics of Nanostructures

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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A Mössbauer study of Fe3-xAlxO4 and Fe3-xGaxO4 has been undertaken. Measurements at low temperatures in magnetic fields enabled us to better separate the Fe(A) and Fe(B) subspectra and to determine the cation distribution on tetrahedral and octahedral sites. Whereas Al up to x=1.4 shows a strong preference for B sites, giving rise to a normalization of the spinel structure with Fe2+ located mainly in tetrahedral sites, Ga distributes over both A and B places without tendency towards normalization at least below x¿1.2.

Originele taal-2	Engels
Pagina's (van-tot)	3740-3742
Aantal pagina's	3
Tijdschrift	Journal of Applied Physics
Volume	57
Nummer van het tijdschrift	8
DOI's	https://doi.org/10.1063/1.334954
Status	Gepubliceerd - 1985

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abstract = "A M{\"o}ssbauer study of Fe3-xAlxO4 and Fe3-xGaxO4 has been undertaken. Measurements at low temperatures in magnetic fields enabled us to better separate the Fe(A) and Fe(B) subspectra and to determine the cation distribution on tetrahedral and octahedral sites. Whereas Al up to x=1.4 shows a strong preference for B sites, giving rise to a normalization of the spinel structure with Fe2+ located mainly in tetrahedral sites, Ga distributes over both A and B places without tendency towards normalization at least below x¿1.2.",

author = "M. Rosenberg and P. Deppe and H.U. Janssen and V.A.M. Brabers and F.S. Li and S. Dey",

year = "1985",

doi = "10.1063/1.334954",

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T1 - A Mössbauer study of Al and Ga substituted magnetite

AU - Rosenberg, M.

AU - Deppe, P.

AU - Janssen, H.U.

AU - Brabers, V.A.M.

AU - Li, F.S.

AU - Dey, S.

PY - 1985

Y1 - 1985

N2 - A Mössbauer study of Fe3-xAlxO4 and Fe3-xGaxO4 has been undertaken. Measurements at low temperatures in magnetic fields enabled us to better separate the Fe(A) and Fe(B) subspectra and to determine the cation distribution on tetrahedral and octahedral sites. Whereas Al up to x=1.4 shows a strong preference for B sites, giving rise to a normalization of the spinel structure with Fe2+ located mainly in tetrahedral sites, Ga distributes over both A and B places without tendency towards normalization at least below x¿1.2.

AB - A Mössbauer study of Fe3-xAlxO4 and Fe3-xGaxO4 has been undertaken. Measurements at low temperatures in magnetic fields enabled us to better separate the Fe(A) and Fe(B) subspectra and to determine the cation distribution on tetrahedral and octahedral sites. Whereas Al up to x=1.4 shows a strong preference for B sites, giving rise to a normalization of the spinel structure with Fe2+ located mainly in tetrahedral sites, Ga distributes over both A and B places without tendency towards normalization at least below x¿1.2.

U2 - 10.1063/1.334954

DO - 10.1063/1.334954

M3 - Article

SN - 0021-8979

VL - 57

SP - 3740

EP - 3742

JO - Journal of Applied Physics

JF - Journal of Applied Physics

IS - 8

ER -

A Mössbauer study of Al and Ga substituted magnetite

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