2-(Trimethylsilyl)-λ3-Phosphinine: synthesis, coordination chemistry, and reactivity

Marija H. Habicht, Friedrich Wossidlo, Tobias Bens, Evgeny A. Pidko, Christian Müller

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelpeer review

23 Citaten (Scopus)
2 Downloads (Pure)

Samenvatting

The [4+2] cycloaddition reaction between 2-pyrone and Me3Si−C≡P gives the corresponding 2-(trimethylsilyl)-λ3-phosphinine in good yields as a rather air and moisture stable, colorless oil. Insight into the regioselectivity of the pericyclic reaction was obtained with the help of deuterium-labeling experiments. The silyl-phosphinine acts as a ligand for the preparation of a Cu(I) and the first crystallographically characterized phosphinine-Ag(I) complex. The title compound was further used as a starting material for an alternative preparation of the parent phosphinine C5H5P by means of protodesilylation with HCl. C5H5P reacts with CuBr⋅S(CH3)2 to give an infinite Cu(I)Br coordination polymer. DFT calculations shed light on the influence of the -Si(CH3)3 group on the electronic properties of the aromatic phosphorus heterocycle.

Originele taal-2Engels
Pagina's (van-tot)944-952
Aantal pagina's9
TijdschriftChemistry : A European Journal
Volume24
Nummer van het tijdschrift4
DOI's
StatusGepubliceerd - 19 jan 2018
Extern gepubliceerdJa

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