2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)

A. Campos Carrasco; E.A. Pidko; A.M. Masdeu-Bultó; M. Lutz; A.L. Spek; D. Vogt; C. Müller

doi:10.1039/c0nj00030b

2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)

A. Campos Carrasco
, E.A. Pidko
, A.M. Masdeu-Bultó
, M. Lutz
, A.L. Spek
, D. Vogt
, C. Müller

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

37 Citaten (Scopus)

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The coordination chemistry of the bidentate P,N hybrid ligand 2-(2-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

Originele taal-2	Engels
Pagina's (van-tot)	1547-1550
Aantal pagina's	4
Tijdschrift	New Journal of Chemistry
Volume	34
Nummer van het tijdschrift	8
DOI's	https://doi.org/10.1039/c0nj00030b
Status	Gepubliceerd - 2010

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@article{37086bcda11e4b938dc846af8effddfc,

title = "2-(2{\textquoteright}-pyridyl)-4,6-diphenylphosphinine versus 2-(2{\textquoteright}-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)",

abstract = "The coordination chemistry of the bidentate P,N hybrid ligand 2-(2-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.",

author = "\{Campos Carrasco\}, A. and E.A. Pidko and A.M. Masdeu-Bult{\'o} and M. Lutz and A.L. Spek and D. Vogt and C. M{\"u}ller",

year = "2010",

doi = "10.1039/c0nj00030b",

language = "English",

volume = "34",

pages = "1547--1550",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "8",

}

2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I). / Campos Carrasco, A.; Pidko, E.A.; Masdeu-Bultó, A.M. et al.
In: New Journal of Chemistry, Vol. 34, Nr. 8, 2010, blz. 1547-1550.

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

TY - JOUR

T1 - 2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)

AU - Campos Carrasco, A.

AU - Pidko, E.A.

AU - Masdeu-Bultó, A.M.

AU - Lutz, M.

AU - Spek, A.L.

AU - Vogt, D.

AU - Müller, C.

PY - 2010

Y1 - 2010

N2 - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

AB - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

U2 - 10.1039/c0nj00030b

DO - 10.1039/c0nj00030b

M3 - Article

SN - 1144-0546

VL - 34

SP - 1547

EP - 1550

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)

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