2-(2’-pyridyl)-4,6-diphenylphosphinine versus 2-(2’-pyridyl)-4,6- diphenylpyridine: An evaluation of their coordination chemistry towards Rh(I)

A. Campos Carrasco, E.A. Pidko, A.M. Masdeu-Bultó, M. Lutz, A.L. Spek, D. Vogt, C. Müller

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelpeer review

32 Citaten (Scopus)

Samenvatting

The coordination chemistry of the bidentate P,N hybrid ligand 2-(2-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.
Originele taal-2Engels
Pagina's (van-tot)1547-1550
Aantal pagina's4
TijdschriftNew Journal of Chemistry
Volume34
Nummer van het tijdschrift8
DOI's
StatusGepubliceerd - 2010

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