Zero-shear stress relaxation and long time dynamics of a linear polyethylene melt: A test of Rouse theory

J.T. Padding; W.J. Briels

doi:10.1063/1.1368135

Zero-shear stress relaxation and long time dynamics of a linear polyethylene melt: A test of Rouse theory

J.T. Padding, W.J. Briels

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Abstract

Molecular dynamics (MD) simulations of a polyethylene melt were performed to investigate the validity of the Rouse model predictions for a comprehensive set of correlation functions. It was found that the chains behave like Rouse theory predicts, but only on length scales larger than the segment length.

Original language	English
Pages (from-to)	8685-8693
Number of pages	9
Journal	Journal of Chemical Physics
Volume	114
Issue number	19
DOIs	https://doi.org/10.1063/1.1368135
Publication status	Published - 2001

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title = "Zero-shear stress relaxation and long time dynamics of a linear polyethylene melt: A test of Rouse theory",

abstract = "Molecular dynamics (MD) simulations of a polyethylene melt were performed to investigate the validity of the Rouse model predictions for a comprehensive set of correlation functions. It was found that the chains behave like Rouse theory predicts, but only on length scales larger than the segment length.",

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M3 - Article

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 19

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Zero-shear stress relaxation and long time dynamics of a linear polyethylene melt: A test of Rouse theory

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