Z-E conformational isomerism of nerol, geraniol, and their acetates

J.W. Haan, de; L.J.M. Ven, van de

doi:10.1016/S0040-4039(01)96957-6

Z-E conformational isomerism of nerol, geraniol, and their acetates

J.W. Haan, de
, L.J.M. Ven, van de

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

Original language	English
Pages (from-to)	2703-2706
Number of pages	4
Journal	Tetrahedron Letters
Volume	12
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(01)96957-6
Publication status	Published - 1971

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title = "Z-E conformational isomerism of nerol, geraniol, and their acetates",

abstract = "NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]",

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year = "1971",

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journal = "Tetrahedron Letters",

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T1 - Z-E conformational isomerism of nerol, geraniol, and their acetates

AU - Haan, de, J.W.

AU - Ven, van de, L.J.M.

PY - 1971

Y1 - 1971

N2 - NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

AB - NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

U2 - 10.1016/S0040-4039(01)96957-6

DO - 10.1016/S0040-4039(01)96957-6

M3 - Article

SN - 0040-4039

VL - 12

SP - 2703

EP - 2706

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 29

ER -

Z-E conformational isomerism of nerol, geraniol, and their acetates

Abstract

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