X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation

A.C. Bellaart, D. van Aken, H.M. Buck, C.H. Stam, A.M. Herk, van

Research output: Contribution to journalArticleAcademicpeer-review

8 Citations (Scopus)

Abstract

The phosphite triester (6), the O,O,O-thiophosphate triester (7), and the phosphate triester (8) of methyl ß-d-ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X-ray diffraction. Quantum-chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.
Original languageEnglish
Pages (from-to)523-526
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume98
Issue number11
DOIs
Publication statusPublished - 1979

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