X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation

A.C. Bellaart; D. van Aken; H.M. Buck; C.H. Stam; A.M. Herk, van

doi:10.1002/recl.19790981102

X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation

A.C. Bellaart, D. van Aken, H.M. Buck, C.H. Stam, A.M. Herk, van

Chemical Engineering and Chemistry

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Abstract

The phosphite triester (6), the O,O,O-thiophosphate triester (7), and the phosphate triester (8) of methyl ß-d-ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X-ray diffraction. Quantum-chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.

Original language	English
Pages (from-to)	523-526
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	98
Issue number	11
DOIs	https://doi.org/10.1002/recl.19790981102
Publication status	Published - 1979

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title = "X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation",

abstract = "The phosphite triester (6), the O,O,O-thiophosphate triester (7), and the phosphate triester (8) of methyl {\ss}-d-ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X-ray diffraction. Quantum-chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.",

author = "A.C. Bellaart and {van Aken}, D. and H.M. Buck and C.H. Stam and {Herk, van}, A.M.",

year = "1979",

doi = "10.1002/recl.19790981102",

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T1 - X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation

AU - Bellaart, A.C.

AU - van Aken, D.

AU - Buck, H.M.

AU - Stam, C.H.

AU - Herk, van, A.M.

PY - 1979

Y1 - 1979

N2 - The phosphite triester (6), the O,O,O-thiophosphate triester (7), and the phosphate triester (8) of methyl ß-d-ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X-ray diffraction. Quantum-chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.

AB - The phosphite triester (6), the O,O,O-thiophosphate triester (7), and the phosphate triester (8) of methyl ß-d-ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X-ray diffraction. Quantum-chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.

U2 - 10.1002/recl.19790981102

DO - 10.1002/recl.19790981102

M3 - Article

SN - 0165-0513

VL - 98

SP - 523

EP - 526

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 11

ER -

X-ray structure determination of the phosphite triester of methyl b-D-ribopyranoside; CNDO-2 calculation

Abstract

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