Wavelength-Selective Photopolymerization of Hybrid Acrylate-Oxetane Liquid Crystals

Davey C. Hoekstra, B.P.A.C. van der Lubbe, A.B.P. (Tom) Bus, Lanti Yang, Nadia Grossiord, Michael G. Debije, Albert P.H.J. Schenning (Corresponding author)

Research output: Contribution to journalArticleAcademicpeer-review

7 Citations (Scopus)


We report on the wavelength-selective photopolymerization of a hybrid acrylate-oxetane cholesteric liquid crystal monomer mixture. By controlling the sequence and rate of the orthogonal free-radical and cationic photopolymerization reactions, it is possible to control the degree of phase separation in the resulting liquid crystal interpenetrating networks. We show that this can be used to tune the reflective color of the structurally colored coatings produced. Conversely, the structural color can be used to monitor the degree of phase separation. Our new photopolymerization procedure allows for structuring liquid crystal networks in three dimensions, which has great potential for fabricating liquid crystal polymer materials with programmable functional properties.

Original languageEnglish
Pages (from-to)10935-10941
Number of pages7
JournalAngewandte Chemie - International Edition
Issue number19
Publication statusPublished - 3 May 2021


  • cholesteric liquid crystals
  • in situ characterization
  • interpenetrating polymer networks
  • phase separation
  • photopolymerization


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