Vibrational dephasing mechanisms in hydrogen-bonded systems

M. Bonn; M.J.P. Brugmans; A.W. Kleyn; R.A. Santen, van; H.J. Bakker

doi:10.1103/PhysRevLett.76.2440

Vibrational dephasing mechanisms in hydrogen-bonded systems

M. Bonn, M.J.P. Brugmans, A.W. Kleyn, R.A. Santen, van, H.J. Bakker

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

32 Citations (Scopus)

198 Downloads (Pure)

Abstract

With transient IR hole-burning spectroscopy we observe large variations in the homogeneous linewidth 1 of the nu(s)(O-D) stretch vibration of differently hydrogen-bonded surface hydroxyls in zeolite catalysts. The linewidth is very sensitive to the frequency of the nu(sigma)(OD ... X) hydrogen-bond vibration. By varying this frequency we obtain conclusive information on the coupling between the nu(s)(O-D) and the nu(sigma)(OD ... X) modes

Original language	English
Pages (from-to)	2440-2443
Number of pages	4
Journal	Physical Review Letters
Volume	76
Issue number	14
DOIs	https://doi.org/10.1103/PhysRevLett.76.2440
Publication status	Published - 1996

Access to Document

10.1103/PhysRevLett.76.2440

590972Final published version, 151 KB

Cite this

@article{c33b6f7ee24248fca7bf691f51b687c7,

title = "Vibrational dephasing mechanisms in hydrogen-bonded systems",

abstract = "With transient IR hole-burning spectroscopy we observe large variations in the homogeneous linewidth 1 of the nu(s)(O-D) stretch vibration of differently hydrogen-bonded surface hydroxyls in zeolite catalysts. The linewidth is very sensitive to the frequency of the nu(sigma)(OD ... X) hydrogen-bond vibration. By varying this frequency we obtain conclusive information on the coupling between the nu(s)(O-D) and the nu(sigma)(OD ... X) modes",

author = "M. Bonn and M.J.P. Brugmans and A.W. Kleyn and {Santen, van}, R.A. and H.J. Bakker",

year = "1996",

doi = "10.1103/PhysRevLett.76.2440",

language = "English",

volume = "76",

pages = "2440--2443",

journal = "Physical Review Letters",

issn = "0031-9007",

publisher = "American Physical Society",

number = "14",

}

TY - JOUR

T1 - Vibrational dephasing mechanisms in hydrogen-bonded systems

AU - Bonn, M.

AU - Brugmans, M.J.P.

AU - Kleyn, A.W.

AU - Santen, van, R.A.

AU - Bakker, H.J.

PY - 1996

Y1 - 1996

N2 - With transient IR hole-burning spectroscopy we observe large variations in the homogeneous linewidth 1 of the nu(s)(O-D) stretch vibration of differently hydrogen-bonded surface hydroxyls in zeolite catalysts. The linewidth is very sensitive to the frequency of the nu(sigma)(OD ... X) hydrogen-bond vibration. By varying this frequency we obtain conclusive information on the coupling between the nu(s)(O-D) and the nu(sigma)(OD ... X) modes

AB - With transient IR hole-burning spectroscopy we observe large variations in the homogeneous linewidth 1 of the nu(s)(O-D) stretch vibration of differently hydrogen-bonded surface hydroxyls in zeolite catalysts. The linewidth is very sensitive to the frequency of the nu(sigma)(OD ... X) hydrogen-bond vibration. By varying this frequency we obtain conclusive information on the coupling between the nu(s)(O-D) and the nu(sigma)(OD ... X) modes

U2 - 10.1103/PhysRevLett.76.2440

DO - 10.1103/PhysRevLett.76.2440

M3 - Article

C2 - 10060700

SN - 0031-9007

VL - 76

SP - 2440

EP - 2443

JO - Physical Review Letters

JF - Physical Review Letters

IS - 14

ER -

Vibrational dephasing mechanisms in hydrogen-bonded systems

Abstract

Access to Document

Fingerprint

Cite this