Vapor-liquid equilibria of the binary system 1,5-hexadiene + allyl chloride

S. Raeissi, L.J. Florusse, C.J. Peters

    Research output: Contribution to journalArticleAcademicpeer-review

    1 Citation (Scopus)

    Abstract

    Knowledge of accurate vapor–liquid equilibrium data for mixtures of allyl chloride and 1,5-hexadiene is important for several industrial purposes. The bubble points of binary mixtures of allyl chloride and 1,5-hexadiene have been measured experimentally using a synthetic method. Measurements were carried over concentrations ranging from (0 to 1) mol % of allyl chloride. The vapor–liquid equilibrium is presented at temperatures ranging from (25 to 100) °C. Within this temperature range, bubble-point pressures up to 5 bar were observed. The experimental results indicated that, as the concentration of allyl chloride increases in the mixture, higher pressures are necessary for a complete dissolution of the two components. In addition, solubility pressures increase as temperature increases for a mixture of fixed composition
    Original languageEnglish
    Pages (from-to)52-55
    Number of pages4
    JournalJournal of Chemical and Engineering Data
    Volume59
    DOIs
    Publication statusPublished - 2014

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