Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La)

D. De Graaf, H. T. Hintzen, R. Metselaar, G. de With

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

1 Citation (Scopus)

Abstract

The luminescence characteristics of Ce3+ doped M-Si-Al-O-N glasses (M = Sc, Y, La, Gd) have been examined by means of fluorospectrometry. It was found that the emission energy is strongly dependent on the composition of the glass and in particular to the cerium content of the glass. With increasing cerium content the emission shifts to longer wavelengths. This emission shift is ascribed to energy transfer, which explains the dependence of the emission wavelength on the cerium concentration. Evidence was found for the existence of multiple cerium sites in the glasses; some of which are preliminary attributed to cerium clusters or pairs.

Original languageEnglish
Title of host publicationProceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society
Place of PublicationUetikon-Zürich
PublisherTrans Tech Publications
Pages2065-2068
Number of pages4
DOIs
Publication statusPublished - 2002
Event7th Conference and Exhibition of the European Ceramic Society (ECerS 2001), September 9-13, 2001, Brugge, Belgium - Brugge, Belgium
Duration: 9 Sep 200113 Sep 2001

Publication series

NameKey Engineering Materials
Volume206-213
ISSN (Print)1013-9826

Conference

Conference7th Conference and Exhibition of the European Ceramic Society (ECerS 2001), September 9-13, 2001, Brugge, Belgium
Abbreviated titleECerS 2001
CountryBelgium
CityBrugge
Period9/09/0113/09/01

Fingerprint

Cerium
Luminescence
Glass
Wavelength
Energy transfer
Chemical analysis

Keywords

  • Glass
  • Luminescence
  • Rare-earths
  • Sialon

Cite this

De Graaf, D., Hintzen, H. T., Metselaar, R., & de With, G. (2002). Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La). In Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society (pp. 2065-2068). (Key Engineering Materials; Vol. 206-213). Uetikon-Zürich: Trans Tech Publications. https://doi.org/10.4028/www.scientific.net/KEM.206-213.2065
De Graaf, D. ; Hintzen, H. T. ; Metselaar, R. ; de With, G. / Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La). Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society. Uetikon-Zürich : Trans Tech Publications, 2002. pp. 2065-2068 (Key Engineering Materials).
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De Graaf, D, Hintzen, HT, Metselaar, R & de With, G 2002, Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La). in Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society. Key Engineering Materials, vol. 206-213, Trans Tech Publications, Uetikon-Zürich, pp. 2065-2068, 7th Conference and Exhibition of the European Ceramic Society (ECerS 2001), September 9-13, 2001, Brugge, Belgium, Brugge, Belgium, 9/09/01. https://doi.org/10.4028/www.scientific.net/KEM.206-213.2065

Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La). / De Graaf, D.; Hintzen, H. T.; Metselaar, R.; de With, G.

Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society. Uetikon-Zürich : Trans Tech Publications, 2002. p. 2065-2068 (Key Engineering Materials; Vol. 206-213).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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AB - The luminescence characteristics of Ce3+ doped M-Si-Al-O-N glasses (M = Sc, Y, La, Gd) have been examined by means of fluorospectrometry. It was found that the emission energy is strongly dependent on the composition of the glass and in particular to the cerium content of the glass. With increasing cerium content the emission shifts to longer wavelengths. This emission shift is ascribed to energy transfer, which explains the dependence of the emission wavelength on the cerium concentration. Evidence was found for the existence of multiple cerium sites in the glasses; some of which are preliminary attributed to cerium clusters or pairs.

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BT - Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society

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De Graaf D, Hintzen HT, Metselaar R, de With G. Unusual luminescence phenomena in Ce(III)-doped M-Si-Al-O-N glasses (M = Sc, Y, Gd, La). In Proceedings the 7th conference and exhibition of the European Ceramic Society, Brugge, Belgium, September 9 - 13, 2001, seventh ECerS / EURO Ceramics VII. Organized by the Belgian Ceramic Society on behalf of the European Ceramic Society. Uetikon-Zürich: Trans Tech Publications. 2002. p. 2065-2068. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.206-213.2065