Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 1735-1738 |
| Number of pages | 4 |
| Journal | ChemCatChem |
| Volume | 3 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2011 |
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Unprecedented oxygenate selectivity in aqueous-phase Fischer-Tropsch synthesis by ruthenium nanoparticles. / Quek, X.Y.; Guan, Y.; Santen, van, R.A.; Hensen, E.J.M.
In: ChemCatChem, Vol. 3, No. 11, 2011, p. 1735-1738.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - Unprecedented oxygenate selectivity in aqueous-phase Fischer-Tropsch synthesis by ruthenium nanoparticles
AU - Quek, X.Y.
AU - Guan, Y.
AU - Santen, van, R.A.
AU - Hensen, E.J.M.
PY - 2011
Y1 - 2011
N2 - Not just for anglers: An unprecedented oxygenate selectivity of 70¿% in the Fischer–Tropsch synthesis is achieved by using a Ru nanoparticle catalyst in the aqueous phase. A kinetic analysis of the anomalous temperature dependence of the chain growth probability shows that hydrocarbons and oxygenates are formed on different sites. Oxygenates (hydrocarbons) form on sites with high (low) barrier for CO dissociation.
AB - Not just for anglers: An unprecedented oxygenate selectivity of 70¿% in the Fischer–Tropsch synthesis is achieved by using a Ru nanoparticle catalyst in the aqueous phase. A kinetic analysis of the anomalous temperature dependence of the chain growth probability shows that hydrocarbons and oxygenates are formed on different sites. Oxygenates (hydrocarbons) form on sites with high (low) barrier for CO dissociation.
U2 - 10.1002/cctc.201100219
DO - 10.1002/cctc.201100219
M3 - Article
VL - 3
SP - 1735
EP - 1738
JO - ChemCatChem
JF - ChemCatChem
SN - 1867-3899
IS - 11
ER -