Unprecedented oxygenate selectivity in aqueous-phase Fischer-Tropsch synthesis by ruthenium nanoparticles

X.Y. Quek; Y. Guan; R.A. Santen, van; E.J.M. Hensen

doi:10.1002/cctc.201100219

Unprecedented oxygenate selectivity in aqueous-phase Fischer-Tropsch synthesis by ruthenium nanoparticles

X.Y. Quek, Y. Guan, R.A. Santen, van, E.J.M. Hensen

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Not just for anglers: An unprecedented oxygenate selectivity of 70¿% in the Fischer–Tropsch synthesis is achieved by using a Ru nanoparticle catalyst in the aqueous phase. A kinetic analysis of the anomalous temperature dependence of the chain growth probability shows that hydrocarbons and oxygenates are formed on different sites. Oxygenates (hydrocarbons) form on sites with high (low) barrier for CO dissociation.

Original language	English
Pages (from-to)	1735-1738
Number of pages	4
Journal	ChemCatChem
Volume	3
Issue number	11
DOIs	https://doi.org/10.1002/cctc.201100219
Publication status	Published - 2011

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title = "Unprecedented oxygenate selectivity in aqueous-phase Fischer-Tropsch synthesis by ruthenium nanoparticles",

abstract = "Not just for anglers: An unprecedented oxygenate selectivity of 70¿% in the Fischer–Tropsch synthesis is achieved by using a Ru nanoparticle catalyst in the aqueous phase. A kinetic analysis of the anomalous temperature dependence of the chain growth probability shows that hydrocarbons and oxygenates are formed on different sites. Oxygenates (hydrocarbons) form on sites with high (low) barrier for CO dissociation.",

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