Understanding FTS selectivity: the crucial role of surface hydrogen

C.J. Weststrate (Corresponding author), J.W. Niemantsverdriet

Research output: Contribution to journalArticleAcademicpeer-review

11 Citations (Scopus)

Abstract

Monomeric forms of carbon play a central role in the synthesis of long chain hydrocarbons via the Fischer-Tropsch synthesis (FTS). We explored the chemistry of C1Hxad species on the close-packed surface of cobalt. Our findings on this simple model catalyst highlight the important role of surface hydrogen and vacant sites for product selectivity. We furthermore find that COad affects hydrogen in multiple ways. It limits the adsorption capacity for Had, lowers its adsorption energy and inhibits dissociative H2 adsorption. We discuss how these findings, extrapolated to pressures and temperatures used in applied FTS, can provide insights into the correlation between partial pressure of reactants and product selectivity. By combining the C1Hx stability differences found in the present work with literature reports of the reactivity of C1Hx species measured by steady state isotope transient kinetic analysis, we aim to shed light on the nature of the atomic carbon reservoir found in these studies.

Original languageEnglish
Pages (from-to)101-116
Number of pages16
JournalFaraday Discussions
Volume197
DOIs
Publication statusPublished - 28 Apr 2017

Fingerprint Dive into the research topics of 'Understanding FTS selectivity: the crucial role of surface hydrogen'. Together they form a unique fingerprint.

  • Cite this