Abstract
A new two-stage synthesis of double molybdenum and nickel carbides and high-activity and stable catalytic coatings of nickel-promoter molybdenum carbides in salt melts is developed. The first stage includes the formation of molybdenum-nickel alloys by an electrolytic method and currentless transfer in chloride melts. The second stage consists in the carbonization of the alloys in a chloride-carbonate melt under various synthesis conditions. The stabilities of the nickel-promoter catalytic systems are studied, and their catalytic activities in the back water-gas shift reaction are determined.
| Original language | English |
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| Pages (from-to) | 767-773 |
| Journal | Russian Metallurgy (Metally) |
| Volume | 8 |
| Publication status | Published - 2011 |