Tuning the electronic effects of aromatic phosphorus heterocycles: An unprecedented phosphinine with significant P(π)-donor properties

A. Loibl, I. de Krom, E.A. Pidko, M. Weber, J. Wiecko, C. Müller

Research output: Contribution to journalArticleAcademicpeer-review

31 Citations (Scopus)
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Abstract

A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic properties of this low-coordinate and aromatic phosphorus heterocycle substantially. This journal is

Original languageEnglish
Pages (from-to)8842-8844
Number of pages3
JournalChemical Communications
Volume50
Issue number64
DOIs
Publication statusPublished - 18 Aug 2014

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