Triads Containing Terpyridine-Ruthenium(II) Complexes and the Perylene Fluorescent Dye

H. Hofmeier, P.R. Andres, U.S. Schubert

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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2 Downloads (Pure)

Abstract

A perylene unit was modified with two terpyridine moieties. Each terpyridine chelating moiety was subsequently complexed with ruthenium(III) trichloride to yield a dinuclear bis(monoterpyridine-ruthenium(III) chloride)perylene derivative. Alternatively, it is possible to obtain the corresponding perylene derivative bearing two bis-terpyridine-ruthenium(II) complexes via conversion of the of the terpyridine-substituted perylene with [Ru(tpy)Cl3]. The compounds were characterized in detail by MALDI-TOF mass spectrometry, NMR, UV-vis as well as fluorescence spectroscopy.
Original languageEnglish
Title of host publicationMetal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]
EditorsU.S. Schubert, G.R. Newkome
Place of PublicationWashington, DC
PublisherAmerican Chemical Society
Pages86-96
ISBN (Print)0-8412-3929-0
DOIs
Publication statusPublished - 2006
EventMetal-Containing and Metallosupramolecular Polymers and Materials - Anaheim, United States
Duration: 28 Mar 20041 Apr 2004

Publication series

NameACS Symposium Series
Volume928
ISSN (Print)0097-6156

Conference

ConferenceMetal-Containing and Metallosupramolecular Polymers and Materials
CountryUnited States
CityAnaheim
Period28/03/041/04/04
OtherSymposium in spring 2004 during the 227th ACS National Meeting

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    Hofmeier, H., Andres, P. R., & Schubert, U. S. (2006). Triads Containing Terpyridine-Ruthenium(II) Complexes and the Perylene Fluorescent Dye. In U. S. Schubert, & G. R. Newkome (Eds.), Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California] (pp. 86-96). (ACS Symposium Series; Vol. 928). American Chemical Society. https://doi.org/10.1021/bk-2006-0928.ch007