Towards selective ethylene tetramerization

S. Licciulli; I. Thapa; K. Albahily; I.V. Korobkov; S. Gambarotta; R. Duchateau; R. Chevalier; K. Schuhen

doi:10.1002/anie.201003465

Towards selective ethylene tetramerization

S. Licciulli
, I. Thapa
, K. Albahily
, I.V. Korobkov
, S. Gambarotta
, R. Duchateau
, R. Chevalier
, K. Schuhen

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

80 Citations (Scopus)

Abstract

And the magic number is … 4! A large amount of oligomer-free 1-octene (99.9¿%) was produced from ethylene by a catalytic system based on chromium during the formation of polyethylene wax [see GC–MS chromatogram; the other three significant peaks are methanol (quenching agent), ethyl acetate (needle-rinsing agent), and toluene (solvent)].

Original language	English
Pages (from-to)	9225-9228
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	48
DOIs	https://doi.org/10.1002/anie.201003465
Publication status	Published - 2010

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10.1002/anie.201003465

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title = "Towards selective ethylene tetramerization",

abstract = "And the magic number is … 4! A large amount of oligomer-free 1-octene (99.9¿\%) was produced from ethylene by a catalytic system based on chromium during the formation of polyethylene wax [see GC–MS chromatogram; the other three significant peaks are methanol (quenching agent), ethyl acetate (needle-rinsing agent), and toluene (solvent)].",

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AU - Licciulli, S.

AU - Thapa, I.

AU - Albahily, K.

AU - Korobkov, I.V.

AU - Gambarotta, S.

AU - Duchateau, R.

AU - Chevalier, R.

AU - Schuhen, K.

PY - 2010

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AB - And the magic number is … 4! A large amount of oligomer-free 1-octene (99.9¿%) was produced from ethylene by a catalytic system based on chromium during the formation of polyethylene wax [see GC–MS chromatogram; the other three significant peaks are methanol (quenching agent), ethyl acetate (needle-rinsing agent), and toluene (solvent)].

U2 - 10.1002/anie.201003465

DO - 10.1002/anie.201003465

M3 - Article

C2 - 20963738

SN - 0570-0833

VL - 49

SP - 9225

EP - 9228

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 48

ER -

Towards selective ethylene tetramerization

Abstract

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