Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts

H.F.J. Blik, van 't, P.H.A. Vriens, R. Prins

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

Abstract

A fast as well as a slow component was observed in the room temperature adsorption of H2 and O2 on Rh on rutile and anatase TiO2 catalysts. Both components of the H2 adsorption decreased in magnitude with increasing catalyst reduction temperature, while the fast O2 adsorption increased in magnitude and the slow O2 adsorption stayed constant. The fast H2 adsorption proved to be due to chemisorption on the metal and the slow H2 adsorption to spillover from the metal to the support. The fast O2 adsorption was due to chemisorption on the metal as well as on the support, with the concurrent reoxidation of Ti3+ ions formed during H-spillover. The slow O2 adsorption was caused by corrosive chemisorption of the metal particles.
Original languageEnglish
Title of host publicationStrong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985
EditorsR.T.K. Baker, S.J. Tauster, J.A. Dumesic
Place of PublicationWashington, DC
PublisherAmerican Chemical Society
Pages60-75
ISBN (Print)978-0-8412-0955-8
DOIs
Publication statusPublished - 1986

Publication series

NameACS Symposium Series
Volume298
ISSN (Print)0097-6156

Fingerprint

Rhodium
Chemisorption
Hydrogen
Oxygen
Adsorption
Catalysts
Metals
Caustics
titanium dioxide
Ions
Temperature

Cite this

Blik, van 't, H. F. J., Vriens, P. H. A., & Prins, R. (1986). Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts. In R. T. K. Baker, S. J. Tauster, & J. A. Dumesic (Eds.), Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985 (pp. 60-75). (ACS Symposium Series; Vol. 298). Washington, DC: American Chemical Society. https://doi.org/10.1021/bk-1986-0298.ch007
Blik, van 't, H.F.J. ; Vriens, P.H.A. ; Prins, R. / Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts. Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985. editor / R.T.K. Baker ; S.J. Tauster ; J.A. Dumesic. Washington, DC : American Chemical Society, 1986. pp. 60-75 (ACS Symposium Series).
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abstract = "A fast as well as a slow component was observed in the room temperature adsorption of H2 and O2 on Rh on rutile and anatase TiO2 catalysts. Both components of the H2 adsorption decreased in magnitude with increasing catalyst reduction temperature, while the fast O2 adsorption increased in magnitude and the slow O2 adsorption stayed constant. The fast H2 adsorption proved to be due to chemisorption on the metal and the slow H2 adsorption to spillover from the metal to the support. The fast O2 adsorption was due to chemisorption on the metal as well as on the support, with the concurrent reoxidation of Ti3+ ions formed during H-spillover. The slow O2 adsorption was caused by corrosive chemisorption of the metal particles.",
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Blik, van 't, HFJ, Vriens, PHA & Prins, R 1986, Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts. in RTK Baker, SJ Tauster & JA Dumesic (eds), Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985. ACS Symposium Series, vol. 298, American Chemical Society, Washington, DC, pp. 60-75. https://doi.org/10.1021/bk-1986-0298.ch007

Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts. / Blik, van 't, H.F.J.; Vriens, P.H.A.; Prins, R.

Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985. ed. / R.T.K. Baker; S.J. Tauster; J.A. Dumesic. Washington, DC : American Chemical Society, 1986. p. 60-75 (ACS Symposium Series; Vol. 298).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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AU - Blik, van 't, H.F.J.

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N2 - A fast as well as a slow component was observed in the room temperature adsorption of H2 and O2 on Rh on rutile and anatase TiO2 catalysts. Both components of the H2 adsorption decreased in magnitude with increasing catalyst reduction temperature, while the fast O2 adsorption increased in magnitude and the slow O2 adsorption stayed constant. The fast H2 adsorption proved to be due to chemisorption on the metal and the slow H2 adsorption to spillover from the metal to the support. The fast O2 adsorption was due to chemisorption on the metal as well as on the support, with the concurrent reoxidation of Ti3+ ions formed during H-spillover. The slow O2 adsorption was caused by corrosive chemisorption of the metal particles.

AB - A fast as well as a slow component was observed in the room temperature adsorption of H2 and O2 on Rh on rutile and anatase TiO2 catalysts. Both components of the H2 adsorption decreased in magnitude with increasing catalyst reduction temperature, while the fast O2 adsorption increased in magnitude and the slow O2 adsorption stayed constant. The fast H2 adsorption proved to be due to chemisorption on the metal and the slow H2 adsorption to spillover from the metal to the support. The fast O2 adsorption was due to chemisorption on the metal as well as on the support, with the concurrent reoxidation of Ti3+ ions formed during H-spillover. The slow O2 adsorption was caused by corrosive chemisorption of the metal particles.

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BT - Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985

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Blik, van 't HFJ, Vriens PHA, Prins R. Time dependence of hydrogen and oxygen chemisorption on rhodium-titania catalysts. In Baker RTK, Tauster SJ, Dumesic JA, editors, Strong metal-support interactions : developed from a symposium sponsored by the Divisions of Petroleum Chemistry, Inc., Industrial and Engineering Chemistry ... at the 189th Meeting of the American Chemical Society, Miami Beach, Florida, April 28 - May 3, 1985. Washington, DC: American Chemical Society. 1986. p. 60-75. (ACS Symposium Series). https://doi.org/10.1021/bk-1986-0298.ch007