Thermal expansion of cubic Si3N4 with the spinel structure

H.T.J.M. Hintzen; M.R.M.M. Hendrix; H.J. Wondergem; C.M. Fang; T. Sekine; G. With, de

doi:10.1016/S0925-8388%2802%2901065-4

Thermal expansion of cubic Si3N4 with the spinel structure

H.T.J.M. Hintzen, M.R.M.M. Hendrix, H.J. Wondergem, C.M. Fang, T. Sekine, G. With, de

Materials and Interface Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

19 Citations (Scopus)

Abstract

The thermal expansion coeff. of cubic Si3N4 with the spinel structure was detd. with high temp. x-ray diffraction. The exptl. value agrees well with the lattice parameter predicted by first principles methods, and is significantly larger than the value for b-Si3N4. This difference is discussed in terms of the chem. bonding in these 2 modifications of Si3N4.

Original language	English
Pages (from-to)	40-42
Journal	Journal of Alloys and Compounds
Volume	351
Issue number	1-2
DOIs	https://doi.org/10.1016/S0925-8388%2802%2901065-4 https://doi.org/10.1016/S0925-8388(02)01065-4
Publication status	Published - 2003

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title = "Thermal expansion of cubic Si3N4 with the spinel structure",

abstract = "The thermal expansion coeff. of cubic Si3N4 with the spinel structure was detd. with high temp. x-ray diffraction. The exptl. value agrees well with the lattice parameter predicted by first principles methods, and is significantly larger than the value for b-Si3N4. This difference is discussed in terms of the chem. bonding in these 2 modifications of Si3N4.",

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AU - Hintzen, H.T.J.M.

AU - Hendrix, M.R.M.M.

AU - Wondergem, H.J.

AU - Fang, C.M.

AU - Sekine, T.

AU - With, de, G.

PY - 2003

Y1 - 2003

N2 - The thermal expansion coeff. of cubic Si3N4 with the spinel structure was detd. with high temp. x-ray diffraction. The exptl. value agrees well with the lattice parameter predicted by first principles methods, and is significantly larger than the value for b-Si3N4. This difference is discussed in terms of the chem. bonding in these 2 modifications of Si3N4.

AB - The thermal expansion coeff. of cubic Si3N4 with the spinel structure was detd. with high temp. x-ray diffraction. The exptl. value agrees well with the lattice parameter predicted by first principles methods, and is significantly larger than the value for b-Si3N4. This difference is discussed in terms of the chem. bonding in these 2 modifications of Si3N4.

U2 - 10.1016/S0925-8388%2802%2901065-4

DO - 10.1016/S0925-8388%2802%2901065-4

M3 - Article

VL - 351

SP - 40

EP - 42

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

IS - 1-2

ER -