Thermal desorption spectroscopy as a quantitative tool to determine the hydrogen content in solids

F. Zeppelin, von; M. Haluska; M. Hirscher

doi:10.1016/S0040-6031(03)00183-7

Thermal desorption spectroscopy as a quantitative tool to determine the hydrogen content in solids

F. Zeppelin, von
, M. Haluska
, M. Hirscher

Energy Technology

Research output: Contribution to journal › Article › Academic › peer-review

84 Citations (Scopus)

1 Downloads (Pure)

Abstract

Thermal desorption spectroscopy (TDS) utilising a quadrupolar mass spectrometer is a highly sensitive and selective method to study the hydrogen desorption of hydrogen storage materials. For a quantitative analysis of the hydrogen storage capacity, the TDS apparatus can be consistently calibrated by using hydrogenated PdGd alloys or TiH2 as standards. Owing to its hygroscopic nature, the use of CaH2 as calibration standard leads to erroneous results. The chemical reactions during the thermal desorption of CaH2 are analysed in detail.

Original language	English
Pages (from-to)	251-258
Journal	Thermochimica Acta
Volume	404
Issue number	1-2
DOIs	https://doi.org/10.1016/S0040-6031(03)00183-7
Publication status	Published - 2003

Access to Document

10.1016/S0040-6031(03)00183-7

Cite this

@article{4c8e397828a24d2dbb142d36e884c450,

title = "Thermal desorption spectroscopy as a quantitative tool to determine the hydrogen content in solids",

abstract = "Thermal desorption spectroscopy (TDS) utilising a quadrupolar mass spectrometer is a highly sensitive and selective method to study the hydrogen desorption of hydrogen storage materials. For a quantitative analysis of the hydrogen storage capacity, the TDS apparatus can be consistently calibrated by using hydrogenated PdGd alloys or TiH2 as standards. Owing to its hygroscopic nature, the use of CaH2 as calibration standard leads to erroneous results. The chemical reactions during the thermal desorption of CaH2 are analysed in detail.",

author = "\{Zeppelin, von\}, F. and M. Haluska and M. Hirscher",

year = "2003",

doi = "10.1016/S0040-6031(03)00183-7",

language = "English",

volume = "404",

pages = "251--258",

journal = "Thermochimica Acta",

issn = "0040-6031",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Thermal desorption spectroscopy as a quantitative tool to determine the hydrogen content in solids

AU - Zeppelin, von, F.

AU - Haluska, M.

AU - Hirscher, M.

PY - 2003

Y1 - 2003

N2 - Thermal desorption spectroscopy (TDS) utilising a quadrupolar mass spectrometer is a highly sensitive and selective method to study the hydrogen desorption of hydrogen storage materials. For a quantitative analysis of the hydrogen storage capacity, the TDS apparatus can be consistently calibrated by using hydrogenated PdGd alloys or TiH2 as standards. Owing to its hygroscopic nature, the use of CaH2 as calibration standard leads to erroneous results. The chemical reactions during the thermal desorption of CaH2 are analysed in detail.

AB - Thermal desorption spectroscopy (TDS) utilising a quadrupolar mass spectrometer is a highly sensitive and selective method to study the hydrogen desorption of hydrogen storage materials. For a quantitative analysis of the hydrogen storage capacity, the TDS apparatus can be consistently calibrated by using hydrogenated PdGd alloys or TiH2 as standards. Owing to its hygroscopic nature, the use of CaH2 as calibration standard leads to erroneous results. The chemical reactions during the thermal desorption of CaH2 are analysed in detail.

U2 - 10.1016/S0040-6031(03)00183-7

DO - 10.1016/S0040-6031(03)00183-7

M3 - Article

SN - 0040-6031

VL - 404

SP - 251

EP - 258

JO - Thermochimica Acta

JF - Thermochimica Acta

IS - 1-2

ER -

Thermal desorption spectroscopy as a quantitative tool to determine the hydrogen content in solids

Abstract

Access to Document

Fingerprint

Cite this