Theoretical study of fluorescence of self-assembling helical supramolecular aggregates

L.P. Dijk, van; P.P.A.M. Schoot, van der; P.A. Bobbert

doi:10.1016/j.synthmet.2009.09.038

Theoretical study of fluorescence of self-assembling helical supramolecular aggregates

L.P. Dijk, van, P.P.A.M. Schoot, van der, P.A. Bobbert

Soft Matter and Biological Physics

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The helical self-assembly of MOPV4 oligomers dissolved in dodecane solution has a large effect on the experimental fluorescence spectra. To describe the change in fluorescence upon aggregation, we combine a statistical mechanical theory describing the helical self-assembly with a tight-binding model to account for the delocalization of the exciton. We find our combined model to describe the red-shift of the main fluorescence peak upon aggregation qualitatively. © 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2384-2386
Journal	Synthetic Metals
Volume	159
Issue number	21-22
DOIs	https://doi.org/10.1016/j.synthmet.2009.09.038
Publication status	Published - 2009

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10.1016/j.synthmet.2009.09.038

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title = "Theoretical study of fluorescence of self-assembling helical supramolecular aggregates",

abstract = "The helical self-assembly of MOPV4 oligomers dissolved in dodecane solution has a large effect on the experimental fluorescence spectra. To describe the change in fluorescence upon aggregation, we combine a statistical mechanical theory describing the helical self-assembly with a tight-binding model to account for the delocalization of the exciton. We find our combined model to describe the red-shift of the main fluorescence peak upon aggregation qualitatively. {\textcopyright} 2009 Elsevier B.V. All rights reserved.",

author = "{Dijk, van}, L.P. and {Schoot, van der}, P.P.A.M. and P.A. Bobbert",

year = "2009",

doi = "10.1016/j.synthmet.2009.09.038",

language = "English",

volume = "159",

pages = "2384--2386",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Theoretical study of fluorescence of self-assembling helical supramolecular aggregates

AU - Dijk, van, L.P.

AU - Schoot, van der, P.P.A.M.

AU - Bobbert, P.A.

PY - 2009

Y1 - 2009

N2 - The helical self-assembly of MOPV4 oligomers dissolved in dodecane solution has a large effect on the experimental fluorescence spectra. To describe the change in fluorescence upon aggregation, we combine a statistical mechanical theory describing the helical self-assembly with a tight-binding model to account for the delocalization of the exciton. We find our combined model to describe the red-shift of the main fluorescence peak upon aggregation qualitatively. © 2009 Elsevier B.V. All rights reserved.

AB - The helical self-assembly of MOPV4 oligomers dissolved in dodecane solution has a large effect on the experimental fluorescence spectra. To describe the change in fluorescence upon aggregation, we combine a statistical mechanical theory describing the helical self-assembly with a tight-binding model to account for the delocalization of the exciton. We find our combined model to describe the red-shift of the main fluorescence peak upon aggregation qualitatively. © 2009 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.synthmet.2009.09.038

DO - 10.1016/j.synthmet.2009.09.038

M3 - Article

SN - 0379-6779

VL - 159

SP - 2384

EP - 2386

JO - Synthetic Metals

JF - Synthetic Metals

IS - 21-22

ER -

Theoretical study of fluorescence of self-assembling helical supramolecular aggregates

Abstract

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