Abstract
The kinetics of the simultaneous isomerization and hydrogenation of glucose are studied, and the experimental results are described with a simplified reaction model. By simulating the course of the reactions with a computer the rate constants were determined, and the energies of activation were calculated. From an Arrhenius plot the apparent isomerization activation energies were deduced. Under the experimental conditions a yield of 27% mannitol was obtained starting from glucose. Higher yields can be obtained at low temperatures and low catalyst concentrations.
Original language | English |
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Pages (from-to) | 199-205 |
Number of pages | 7 |
Journal | Starch ‐ Stärke |
Volume | 30 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1978 |