The role of heterogeneous reactions during the oxidative coupling of methane over Li/MgO catalysts

J.M.N. Kasteren, van; J.W.M.H. Geerts; K. Wiele, van der

doi:10.1016/0920-5861%2890%2985044-O

The role of heterogeneous reactions during the oxidative coupling of methane over Li/MgO catalysts

J.M.N. Kasteren, van
, J.W.M.H. Geerts
, K. Wiele, van der

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The role of heterogeneous and homogeneous reactions in the oxidative coupling of CH4 over Li/MgO was investigated by carrying out expts. at reduced pressure (60 Pa). The radical reactions occurring in the gas phase play an essential role in the C2+ selectivity of the process. A reaction model of consecutive reactions is confirmed. The selectivity of the active catalyst is mainly due to very high rates of Me radical prodn. which couple in the gas phase.

Original language	English
Pages (from-to)	497-502
Journal	Catalysis Today
Volume	6
Issue number	4
DOIs	https://doi.org/10.1016/0920-5861%2890%2985044-O
Publication status	Published - 1990

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title = "The role of heterogeneous reactions during the oxidative coupling of methane over Li/MgO catalysts",

abstract = "The role of heterogeneous and homogeneous reactions in the oxidative coupling of CH4 over Li/MgO was investigated by carrying out expts. at reduced pressure (60 Pa). The radical reactions occurring in the gas phase play an essential role in the C2+ selectivity of the process. A reaction model of consecutive reactions is confirmed. The selectivity of the active catalyst is mainly due to very high rates of Me radical prodn. which couple in the gas phase.",

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AU - Geerts, J.W.M.H.

AU - Wiele, van der, K.

PY - 1990

Y1 - 1990

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AB - The role of heterogeneous and homogeneous reactions in the oxidative coupling of CH4 over Li/MgO was investigated by carrying out expts. at reduced pressure (60 Pa). The radical reactions occurring in the gas phase play an essential role in the C2+ selectivity of the process. A reaction model of consecutive reactions is confirmed. The selectivity of the active catalyst is mainly due to very high rates of Me radical prodn. which couple in the gas phase.

U2 - 10.1016/0920-5861%2890%2985044-O

DO - 10.1016/0920-5861%2890%2985044-O

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VL - 6

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EP - 502

JO - Catalysis Today

JF - Catalysis Today

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ER -

The role of heterogeneous reactions during the oxidative coupling of methane over Li/MgO catalysts

Abstract

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