The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

M. Goesten; E. Stavitski; E.A. Pidko; C. Gücüyener; E. Boshuizen; S.N. Ehrlich; E.J.M. Hensen; F. Kapteijn; J. Gascon

doi:10.1002/chem.201204638

The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

M. Goesten, E. Stavitski, E.A. Pidko, C. Gücüyener, E. Boshuizen, S.N. Ehrlich, E.J.M. Hensen, F. Kapteijn, J. Gascon

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

Original language	English
Pages (from-to)	7809-7816
Number of pages	8
Journal	Chemistry : A European Journal
Volume	19
Issue number	24
DOIs	https://doi.org/10.1002/chem.201204638
Publication status	Published - 2013

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Goesten, M., Stavitski, E., Pidko, E. A., Gücüyener, C., Boshuizen, E., Ehrlich, S. N., Hensen, E. J. M., Kapteijn, F., & Gascon, J. (2013). The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations. Chemistry : A European Journal, 19(24), 7809-7816. https://doi.org/10.1002/chem.201204638

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title = "The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations",

abstract = "We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.",

author = "M. Goesten and E. Stavitski and E.A. Pidko and C. G{\"u}c{\"u}yener and E. Boshuizen and S.N. Ehrlich and E.J.M. Hensen and F. Kapteijn and J. Gascon",

year = "2013",

doi = "10.1002/chem.201204638",

language = "English",

volume = "19",

pages = "7809--7816",

journal = "Chemistry : A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "24",

}

Goesten, M, Stavitski, E, Pidko, EA, Gücüyener, C, Boshuizen, E, Ehrlich, SN, Hensen, EJM, Kapteijn, F & Gascon, J 2013, 'The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations', Chemistry : A European Journal, vol. 19, no. 24, pp. 7809-7816. https://doi.org/10.1002/chem.201204638

The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations. / Goesten, M.; Stavitski, E.; Pidko, E.A. et al.

In: Chemistry : A European Journal, Vol. 19, No. 24, 2013, p. 7809-7816.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

AU - Goesten, M.

AU - Stavitski, E.

AU - Pidko, E.A.

AU - Gücüyener, C.

AU - Boshuizen, E.

AU - Ehrlich, S.N.

AU - Hensen, E.J.M.

AU - Kapteijn, F.

AU - Gascon, J.

PY - 2013

Y1 - 2013

N2 - We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

AB - We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal–organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

U2 - 10.1002/chem.201204638

DO - 10.1002/chem.201204638

M3 - Article

C2 - 23589117

SN - 0947-6539

VL - 19

SP - 7809

EP - 7816

JO - Chemistry : A European Journal

JF - Chemistry : A European Journal

IS - 24

ER -

The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle X-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

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