The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate: Conventional versus microwave heating

M.H.C.L. Dressen; J.E. Stumpel; B.H.P. Kruijs, van de; J. Meuldijk; J.A.J.M. Vekemans; L.A. Hulshof

doi:10.1039/b813030b

The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate: Conventional versus microwave heating

M.H.C.L. Dressen, J.E. Stumpel, B.H.P. Kruijs, van de, J. Meuldijk, J.A.J.M. Vekemans, L.A. Hulshof

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Abstract

The mechanism of the oxidation of benzyl alcohol with iron(III)nitrate nonahydrate under conventional and under microwave heating conditions has been investigated and the reaction conditions have been optimized. A series of redox reactions leads to the formation of benzaldehyde and other products. Direct comparison between conventional and microwave heating revealed identical conversions profiles. Mastering the microwave induced heat, absence of a real microwave effect and byproduct formation are the major factors to advise a traditional batch-wise way of process development to a larger scale. © 2009 The Royal Society of Chemistry

Original language	English
Pages (from-to)	60-64
Journal	Green Chemistry
Volume	11
Issue number	1
DOIs	https://doi.org/10.1039/b813030b
Publication status	Published - 2009

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abstract = "The mechanism of the oxidation of benzyl alcohol with iron(III)nitrate nonahydrate under conventional and under microwave heating conditions has been investigated and the reaction conditions have been optimized. A series of redox reactions leads to the formation of benzaldehyde and other products. Direct comparison between conventional and microwave heating revealed identical conversions profiles. Mastering the microwave induced heat, absence of a real microwave effect and byproduct formation are the major factors to advise a traditional batch-wise way of process development to a larger scale. {\textcopyright} 2009 The Royal Society of Chemistry",

author = "M.H.C.L. Dressen and J.E. Stumpel and {Kruijs, van de}, B.H.P. and J. Meuldijk and J.A.J.M. Vekemans and L.A. Hulshof",

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AU - Dressen, M.H.C.L.

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AU - Meuldijk, J.

AU - Vekemans, J.A.J.M.

AU - Hulshof, L.A.

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AB - The mechanism of the oxidation of benzyl alcohol with iron(III)nitrate nonahydrate under conventional and under microwave heating conditions has been investigated and the reaction conditions have been optimized. A series of redox reactions leads to the formation of benzaldehyde and other products. Direct comparison between conventional and microwave heating revealed identical conversions profiles. Mastering the microwave induced heat, absence of a real microwave effect and byproduct formation are the major factors to advise a traditional batch-wise way of process development to a larger scale. © 2009 The Royal Society of Chemistry

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JF - Green Chemistry

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The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate: Conventional versus microwave heating

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