The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents

T.F.A. Greef, de; M.M.L. Nieuwenhuizen; P.J.M. Stals; C.F.C. Fitié; A.R.A. Palmans; R.P. Sijbesma; E.W. Meijer

doi:10.1039/b806506c

The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents

T.F.A. Greef, de, M.M.L. Nieuwenhuizen, P.J.M. Stals, C.F.C. Fitié, A.R.A. Palmans, R.P. Sijbesma, E.W. Meijer

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Abstract

Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain.

Original language	English
Pages (from-to)	4306-4308
Journal	Chemical Communications, ChemComm
Volume	2008
Issue number	36
DOIs	https://doi.org/10.1039/b806506c
Publication status	Published - 2008

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title = "The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents",

abstract = "Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain.",

author = "{Greef, de}, T.F.A. and M.M.L. Nieuwenhuizen and P.J.M. Stals and C.F.C. Fiti{\'e} and A.R.A. Palmans and R.P. Sijbesma and E.W. Meijer",

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language = "English",

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AU - Greef, de, T.F.A.

AU - Nieuwenhuizen, M.M.L.

AU - Stals, P.J.M.

AU - Fitié, C.F.C.

AU - Palmans, A.R.A.

AU - Sijbesma, R.P.

AU - Meijer, E.W.

PY - 2008

Y1 - 2008

N2 - Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain.

AB - Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain.

U2 - 10.1039/b806506c

DO - 10.1039/b806506c

M3 - Article

C2 - 18802552

SN - 1359-7345

VL - 2008

SP - 4306

EP - 4308

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

IS - 36

ER -

The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents

Abstract

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