The influence of chirality in the amide side chain on the carbonyl orientation in rotational isomers of 3-carbamoylpyridinium halides

L.A.M. Bastiaansen, T.J.M. Vermeulen, H.M. Buck, W.J.J. Smeets, J.A. Kanters

Research output: Contribution to journalArticleAcademicpeer-review

11 Citations (Scopus)

Abstract

The direction of the carbonyl orientation in solid amide rotamers of 3-(N-methyl-N-a-methylbenzylcarbamoyl)-1,2,4-trimethylpyridinium iodide is governed by the (R)- or (S)-chirality in the amide side chain; X-ray structures and c.d. spectra are correlated.
Original languageEnglish
Pages (from-to)230-231
JournalJournal of the Chemical Society, Chemical Communications
Issue number3
DOIs
Publication statusPublished - 1988

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