The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold

M.C. Hermant; M. Verhulst; A.V Kyrylyuk; B. Klumperman; C.E. Koning

doi:10.1016/j.compscitech.2008.12.013

The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold

M.C. Hermant, M. Verhulst, A.V Kyrylyuk, B. Klumperman, C.E. Koning

Research output: Contribution to journal › Article › Academic › peer-review

64 Citations (Scopus)

Abstract

New methods for the incorporation of single-walled carbon nanotubes (SWCNTs) into styrene-divinylbenzene-based high internal phase emulsions (HIPEs) are addressed with specific attention to minimizing the SWCNT loading while maintaining a high level of conductivity of the final polyHIPE-SWCNT composites. Stable HIPEs were achieved using sodium dodecyl sulfate-stabilized SWCNTs, thus eliminating the necessity of SWCNT functionalization. PolyHIPE-SWCNT composites were made with water: oil ratios (vol/vol) of 75:25 and of 84:16. The percolation threshold was determined to be 0.2 and 0.1 wt%, respectively. These threshold values are lower than that obtained for non-porous, polystyrene-SWCNT composites made by means of a latex-based route followed by melt-processing. © 2009 Elsevier Ltd. All rights reserved

Original language	English
Pages (from-to)	656-662
Journal	Composites Science and Technology
Volume	69
Issue number	5
DOIs	https://doi.org/10.1016/j.compscitech.2008.12.013
Publication status	Published - 2009

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title = "The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold",

abstract = "New methods for the incorporation of single-walled carbon nanotubes (SWCNTs) into styrene-divinylbenzene-based high internal phase emulsions (HIPEs) are addressed with specific attention to minimizing the SWCNT loading while maintaining a high level of conductivity of the final polyHIPE-SWCNT composites. Stable HIPEs were achieved using sodium dodecyl sulfate-stabilized SWCNTs, thus eliminating the necessity of SWCNT functionalization. PolyHIPE-SWCNT composites were made with water: oil ratios (vol/vol) of 75:25 and of 84:16. The percolation threshold was determined to be 0.2 and 0.1 wt%, respectively. These threshold values are lower than that obtained for non-porous, polystyrene-SWCNT composites made by means of a latex-based route followed by melt-processing. {\textcopyright} 2009 Elsevier Ltd. All rights reserved",

author = "M.C. Hermant and M. Verhulst and A.V Kyrylyuk and B. Klumperman and C.E. Koning",

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The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold. / Hermant, M.C.; Verhulst, M.; Kyrylyuk, A.V; Klumperman, B.; Koning, C.E.

In: Composites Science and Technology, Vol. 69, No. 5, 2009, p. 656-662.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold

AU - Hermant, M.C.

AU - Verhulst, M.

AU - Kyrylyuk, A.V

AU - Klumperman, B.

AU - Koning, C.E.

PY - 2009

Y1 - 2009

N2 - New methods for the incorporation of single-walled carbon nanotubes (SWCNTs) into styrene-divinylbenzene-based high internal phase emulsions (HIPEs) are addressed with specific attention to minimizing the SWCNT loading while maintaining a high level of conductivity of the final polyHIPE-SWCNT composites. Stable HIPEs were achieved using sodium dodecyl sulfate-stabilized SWCNTs, thus eliminating the necessity of SWCNT functionalization. PolyHIPE-SWCNT composites were made with water: oil ratios (vol/vol) of 75:25 and of 84:16. The percolation threshold was determined to be 0.2 and 0.1 wt%, respectively. These threshold values are lower than that obtained for non-porous, polystyrene-SWCNT composites made by means of a latex-based route followed by melt-processing. © 2009 Elsevier Ltd. All rights reserved

AB - New methods for the incorporation of single-walled carbon nanotubes (SWCNTs) into styrene-divinylbenzene-based high internal phase emulsions (HIPEs) are addressed with specific attention to minimizing the SWCNT loading while maintaining a high level of conductivity of the final polyHIPE-SWCNT composites. Stable HIPEs were achieved using sodium dodecyl sulfate-stabilized SWCNTs, thus eliminating the necessity of SWCNT functionalization. PolyHIPE-SWCNT composites were made with water: oil ratios (vol/vol) of 75:25 and of 84:16. The percolation threshold was determined to be 0.2 and 0.1 wt%, respectively. These threshold values are lower than that obtained for non-porous, polystyrene-SWCNT composites made by means of a latex-based route followed by melt-processing. © 2009 Elsevier Ltd. All rights reserved

U2 - 10.1016/j.compscitech.2008.12.013

DO - 10.1016/j.compscitech.2008.12.013

M3 - Article

VL - 69

SP - 656

EP - 662

JO - Composites Science and Technology

JF - Composites Science and Technology

SN - 0266-3538

IS - 5

ER -