The effect of temperature on the living cationic polymerization of 2-phenyl-2-oxazoline explored utilizing an automated synthesizer

R. Hoogenboom; M.W.M. Fijten; U.S. Schubert

doi:10.1002/marc.200300233

The effect of temperature on the living cationic polymerization of 2-phenyl-2-oxazoline explored utilizing an automated synthesizer

R. Hoogenboom, M.W.M. Fijten, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

48 Citations (Scopus)

Abstract

The temp. dependency of the polymn. of 2-phenyl-2-oxazoline was investigated utilizing a com. available automated synthesizer equipped with individually heatable reactors. Kinetic investigations resulted in an optimal polymn. temp. and activation energy detn. for the polymns. initiated with Me tosylate. Moreover, the in situ generation of benzyl iodide (more reactive initiator) from benzyl chloride and sodium iodide is described, whereby solid sodium iodide was automatically dosed into the reactors

Original language	English
Pages (from-to)	339-343
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	1
DOIs	https://doi.org/10.1002/marc.200300233
Publication status	Published - 2004

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10.1002/marc.200300233

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The effect of temperature on the living cationic polymerization of 2-phenyl-2-oxazoline explored utilizing an automated synthesizer

Abstract

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