The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene

H.R. Reinhoudt, Dick van Langeveld, R. Mariscal, V.H.J. Beer, de, J.A.R. Veen, van, S.T. Sie, J.A. Moulijn

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

Abstract

NiW based hydrotreating catalysts have a good performance in hydrodesulphurisation reactions. It appeared that the their performance in the hydrodesulphurisation of dibenzothiophene and thiophene strongly depends on their sulphiding degree, which can be controlled by both the calcining and sulphiding temperature. By combining temperature programmed sulphiding with quasi in-situ XPS and activity measurements, it was concluded that the active phase for the HDS of DBT consist of either micro-crystalline sulphided Ni on a WO3 substrate, or of Ni2+ dissolved in the in NiWO4. In contrast, the active phase for the HDS of thiophene seems to consist of Ni-promoted WS2 structures.
Original languageEnglish
Title of host publicationHydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997
EditorsG.F. Froment, B. Delmon, P. Grange
Place of PublicationAmsterdam
PublisherElsevier
Pages263-271
ISBN (Print)0-444-82556-8
DOIs
Publication statusPublished - 1997
Eventconference; International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions ; 1 (Oostende) : 1997.02.17-19 -
Duration: 1 Jan 1997 → …

Publication series

NameStudies in Surface Science and Catalysis
Volume106
ISSN (Print)0167-2991

Conference

Conferenceconference; International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions ; 1 (Oostende) : 1997.02.17-19
Period1/01/97 → …
OtherInternational Symposium on Hydrotreatment and Hydrocracking of Oil Fractions ; 1 (Oostende) : 1997.02.17-19

Fingerprint

Thiophenes
Sulfides
Metals
Catalysts
Temperature
X ray photoelectron spectroscopy
Crystalline materials
Substrates
dibenzothiophene

Cite this

Reinhoudt, H. R., van Langeveld, D., Mariscal, R., Beer, de, V. H. J., Veen, van, J. A. R., Sie, S. T., & Moulijn, J. A. (1997). The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene. In G. F. Froment, B. Delmon, & P. Grange (Eds.), Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997 (pp. 263-271). (Studies in Surface Science and Catalysis; Vol. 106). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(97)80023-7
Reinhoudt, H.R. ; van Langeveld, Dick ; Mariscal, R. ; Beer, de, V.H.J. ; Veen, van, J.A.R. ; Sie, S.T. ; Moulijn, J.A. / The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene. Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997. editor / G.F. Froment ; B. Delmon ; P. Grange. Amsterdam : Elsevier, 1997. pp. 263-271 (Studies in Surface Science and Catalysis).
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abstract = "NiW based hydrotreating catalysts have a good performance in hydrodesulphurisation reactions. It appeared that the their performance in the hydrodesulphurisation of dibenzothiophene and thiophene strongly depends on their sulphiding degree, which can be controlled by both the calcining and sulphiding temperature. By combining temperature programmed sulphiding with quasi in-situ XPS and activity measurements, it was concluded that the active phase for the HDS of DBT consist of either micro-crystalline sulphided Ni on a WO3 substrate, or of Ni2+ dissolved in the in NiWO4. In contrast, the active phase for the HDS of thiophene seems to consist of Ni-promoted WS2 structures.",
author = "H.R. Reinhoudt and {van Langeveld}, Dick and R. Mariscal and {Beer, de}, V.H.J. and {Veen, van}, J.A.R. and S.T. Sie and J.A. Moulijn",
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publisher = "Elsevier",
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Reinhoudt, HR, van Langeveld, D, Mariscal, R, Beer, de, VHJ, Veen, van, JAR, Sie, ST & Moulijn, JA 1997, The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene. in GF Froment, B Delmon & P Grange (eds), Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997. Studies in Surface Science and Catalysis, vol. 106, Elsevier, Amsterdam, pp. 263-271, conference; International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions ; 1 (Oostende) : 1997.02.17-19, 1/01/97. https://doi.org/10.1016/S0167-2991(97)80023-7

The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene. / Reinhoudt, H.R.; van Langeveld, Dick; Mariscal, R.; Beer, de, V.H.J.; Veen, van, J.A.R.; Sie, S.T.; Moulijn, J.A.

Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997. ed. / G.F. Froment; B. Delmon; P. Grange. Amsterdam : Elsevier, 1997. p. 263-271 (Studies in Surface Science and Catalysis; Vol. 106).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

TY - GEN

T1 - The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene

AU - Reinhoudt, H.R.

AU - van Langeveld, Dick

AU - Mariscal, R.

AU - Beer, de, V.H.J.

AU - Veen, van, J.A.R.

AU - Sie, S.T.

AU - Moulijn, J.A.

PY - 1997

Y1 - 1997

N2 - NiW based hydrotreating catalysts have a good performance in hydrodesulphurisation reactions. It appeared that the their performance in the hydrodesulphurisation of dibenzothiophene and thiophene strongly depends on their sulphiding degree, which can be controlled by both the calcining and sulphiding temperature. By combining temperature programmed sulphiding with quasi in-situ XPS and activity measurements, it was concluded that the active phase for the HDS of DBT consist of either micro-crystalline sulphided Ni on a WO3 substrate, or of Ni2+ dissolved in the in NiWO4. In contrast, the active phase for the HDS of thiophene seems to consist of Ni-promoted WS2 structures.

AB - NiW based hydrotreating catalysts have a good performance in hydrodesulphurisation reactions. It appeared that the their performance in the hydrodesulphurisation of dibenzothiophene and thiophene strongly depends on their sulphiding degree, which can be controlled by both the calcining and sulphiding temperature. By combining temperature programmed sulphiding with quasi in-situ XPS and activity measurements, it was concluded that the active phase for the HDS of DBT consist of either micro-crystalline sulphided Ni on a WO3 substrate, or of Ni2+ dissolved in the in NiWO4. In contrast, the active phase for the HDS of thiophene seems to consist of Ni-promoted WS2 structures.

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DO - 10.1016/S0167-2991(97)80023-7

M3 - Conference contribution

SN - 0-444-82556-8

T3 - Studies in Surface Science and Catalysis

SP - 263

EP - 271

BT - Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997

A2 - Froment, G.F.

A2 - Delmon, B.

A2 - Grange, P.

PB - Elsevier

CY - Amsterdam

ER -

Reinhoudt HR, van Langeveld D, Mariscal R, Beer, de VHJ, Veen, van JAR, Sie ST et al. The design of base metal catalysts for hydrotreating reactions : temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulfphurisation of thiophene and dibenzothiophene. In Froment GF, Delmon B, Grange P, editors, Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st International Symposium/6th European Workshop, Oostende, Belgium, February 17 - 19, 1997. Amsterdam: Elsevier. 1997. p. 263-271. (Studies in Surface Science and Catalysis). https://doi.org/10.1016/S0167-2991(97)80023-7