The CoO-MoO3/gamma-Al2O3 catalyst : VIII. Analysis of sulfided Co- and Mo-containing catalysts by in situ reflectance spectroscopy

M.J.M. vd Aalst; V.H.J. Beer, de

doi:10.1016/0021-9517%2877%2990264-0

The CoO-MoO3/gamma-Al2O3 catalyst : VIII. Analysis of sulfided Co- and Mo-containing catalysts by in situ reflectance spectroscopy

M.J.M. vd Aalst, V.H.J. Beer, de

Inorganic Materials & Catalysis

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Abstract

Ultraviolet and visible reflectance spectra were recorded in situ for oxidic and sulfided Moand/or Co-containing catalysts supported on alumina and silica. In addition, reflectance spectra of certain selected Mo and Co oxides and sulfides have been included for reference purposes. The results show the formation of MoS2 and Co9S8 in supported systems as a result of sulfidation in H2S/H2. The effect of oxygen chemisorption on sulfided CoO---MoO3/¿-Al2O3 and the effect of Co introduction on the MoS2 phase are discussed.

Original language	English
Pages (from-to)	247-253
Number of pages	7
Journal	Journal of Catalysis
Volume	49
Issue number	3
DOIs	https://doi.org/10.1016/0021-9517%2877%2990264-0 https://doi.org/10.1016/0021-9517(77)90264-0
Publication status	Published - 1977

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title = "The CoO-MoO3/gamma-Al2O3 catalyst : VIII. Analysis of sulfided Co- and Mo-containing catalysts by in situ reflectance spectroscopy",

abstract = "Ultraviolet and visible reflectance spectra were recorded in situ for oxidic and sulfided Moand/or Co-containing catalysts supported on alumina and silica. In addition, reflectance spectra of certain selected Mo and Co oxides and sulfides have been included for reference purposes. The results show the formation of MoS2 and Co9S8 in supported systems as a result of sulfidation in H2S/H2. The effect of oxygen chemisorption on sulfided CoO---MoO3/¿-Al2O3 and the effect of Co introduction on the MoS2 phase are discussed.",

author = "{vd Aalst}, M.J.M. and {Beer, de}, V.H.J.",

year = "1977",

doi = "10.1016/0021-9517%2877%2990264-0",

language = "English",

volume = "49",

pages = "247--253",

journal = "Journal of Catalysis",

issn = "0021-9517",

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T1 - The CoO-MoO3/gamma-Al2O3 catalyst : VIII. Analysis of sulfided Co- and Mo-containing catalysts by in situ reflectance spectroscopy

AU - vd Aalst, M.J.M.

AU - Beer, de, V.H.J.

PY - 1977

Y1 - 1977

N2 - Ultraviolet and visible reflectance spectra were recorded in situ for oxidic and sulfided Moand/or Co-containing catalysts supported on alumina and silica. In addition, reflectance spectra of certain selected Mo and Co oxides and sulfides have been included for reference purposes. The results show the formation of MoS2 and Co9S8 in supported systems as a result of sulfidation in H2S/H2. The effect of oxygen chemisorption on sulfided CoO---MoO3/¿-Al2O3 and the effect of Co introduction on the MoS2 phase are discussed.

AB - Ultraviolet and visible reflectance spectra were recorded in situ for oxidic and sulfided Moand/or Co-containing catalysts supported on alumina and silica. In addition, reflectance spectra of certain selected Mo and Co oxides and sulfides have been included for reference purposes. The results show the formation of MoS2 and Co9S8 in supported systems as a result of sulfidation in H2S/H2. The effect of oxygen chemisorption on sulfided CoO---MoO3/¿-Al2O3 and the effect of Co introduction on the MoS2 phase are discussed.

U2 - 10.1016/0021-9517%2877%2990264-0

DO - 10.1016/0021-9517%2877%2990264-0

M3 - Article

SN - 0021-9517

VL - 49

SP - 247

EP - 253

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 3

ER -

The CoO-MoO3/gamma-Al2O3 catalyst : VIII. Analysis of sulfided Co- and Mo-containing catalysts by in situ reflectance spectroscopy

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