The CoO-MoO3-γ-Al2O3 catalyst: V. Sulfide catalysts promoted by cobalt, nickel, and zinc

V.H.J. Beer, de; T.H.M. Sint Fiet, van; G.H.A.M. vd Steen; A.C. Zwaga; G.C.A. Schuit

doi:10.1016/0021-9517(74)90208-5

The CoO-MoO3-γ-Al2O3 catalyst: V. Sulfide catalysts promoted by cobalt, nickel, and zinc

V.H.J. Beer, de, T.H.M. Sint Fiet, van, G.H.A.M. vd Steen, A.C. Zwaga, G.C.A. Schuit

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Cobalt-, nickel-, and zinc-promoted as well as nonpromoted catalysts based on MoO3, MoS2, and WS2 supported on ¿-Al2O3 and SiO2 have been prepared in three essentially different ways. Their thiophene hydrodesulfurization activities have been determined under continuous flow conditions at atmospheric pressure and 400 °C. Experimental evidence is reported for the relevance of both the monolayer and intercalation model to the preparation and operation of active catalysts. In actual operation the best description of the catalyst is given by the intercalation model.

Original language	English
Pages (from-to)	297-306
Number of pages	10
Journal	Journal of Catalysis
Volume	35
Issue number	2
DOIs	https://doi.org/10.1016/0021-9517(74)90208-5
Publication status	Published - 1974

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title = "The CoO-MoO3-γ-Al2O3 catalyst: V. Sulfide catalysts promoted by cobalt, nickel, and zinc",

abstract = "Cobalt-, nickel-, and zinc-promoted as well as nonpromoted catalysts based on MoO3, MoS2, and WS2 supported on ¿-Al2O3 and SiO2 have been prepared in three essentially different ways. Their thiophene hydrodesulfurization activities have been determined under continuous flow conditions at atmospheric pressure and 400 °C. Experimental evidence is reported for the relevance of both the monolayer and intercalation model to the preparation and operation of active catalysts. In actual operation the best description of the catalyst is given by the intercalation model.",

author = "{Beer, de}, V.H.J. and {Sint Fiet, van}, T.H.M. and {vd Steen}, G.H.A.M. and A.C. Zwaga and G.C.A. Schuit",

year = "1974",

doi = "10.1016/0021-9517(74)90208-5",

language = "English",

volume = "35",

pages = "297--306",

journal = "Journal of Catalysis",

issn = "0021-9517",

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T1 - The CoO-MoO3-γ-Al2O3 catalyst: V. Sulfide catalysts promoted by cobalt, nickel, and zinc

AU - Beer, de, V.H.J.

AU - Sint Fiet, van, T.H.M.

AU - vd Steen, G.H.A.M.

AU - Zwaga, A.C.

AU - Schuit, G.C.A.

PY - 1974

Y1 - 1974

N2 - Cobalt-, nickel-, and zinc-promoted as well as nonpromoted catalysts based on MoO3, MoS2, and WS2 supported on ¿-Al2O3 and SiO2 have been prepared in three essentially different ways. Their thiophene hydrodesulfurization activities have been determined under continuous flow conditions at atmospheric pressure and 400 °C. Experimental evidence is reported for the relevance of both the monolayer and intercalation model to the preparation and operation of active catalysts. In actual operation the best description of the catalyst is given by the intercalation model.

AB - Cobalt-, nickel-, and zinc-promoted as well as nonpromoted catalysts based on MoO3, MoS2, and WS2 supported on ¿-Al2O3 and SiO2 have been prepared in three essentially different ways. Their thiophene hydrodesulfurization activities have been determined under continuous flow conditions at atmospheric pressure and 400 °C. Experimental evidence is reported for the relevance of both the monolayer and intercalation model to the preparation and operation of active catalysts. In actual operation the best description of the catalyst is given by the intercalation model.

U2 - 10.1016/0021-9517(74)90208-5

DO - 10.1016/0021-9517(74)90208-5

M3 - Article

SN - 0021-9517

VL - 35

SP - 297

EP - 306

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 2

ER -

The CoO-MoO3-γ-Al2O3 catalyst: V. Sulfide catalysts promoted by cobalt, nickel, and zinc

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