The chemistry of cycloheptatriene. Part XVI : Sigmatropic shifts of hydrogen in methylcycloheptatriene

A.P. Borg, ter; H. Kloosterziel

doi:10.1002/recl.19690880303

The chemistry of cycloheptatriene. Part XVI : Sigmatropic shifts of hydrogen in methylcycloheptatriene

A.P. Borg, ter, H. Kloosterziel

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

23 Citations (Scopus)

Abstract

Upon heating 7-methylcycloheptatriene, the 3-, 1- and 2-isomers are successively formed by 1-5 shifts of hydrogen. The rate consts. at 140 Deg were detd. Photochem. 1-7 shifts of hydrogen are also reported: the 1-isomer yields preferentially the 7-isomer and little of the 2-isomer, while the 2-isomer yields mainly the 3-isomer and little of the alternative 1-isomer. [on SciFinder (R)]

Original language	English
Pages (from-to)	266-274
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	88
Issue number	3
DOIs	https://doi.org/10.1002/recl.19690880303
Publication status	Published - 1969

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10.1002/recl.19690880303

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title = "The chemistry of cycloheptatriene. Part XVI : Sigmatropic shifts of hydrogen in methylcycloheptatriene",

abstract = "Upon heating 7-methylcycloheptatriene, the 3-, 1- and 2-isomers are successively formed by 1-5 shifts of hydrogen. The rate consts. at 140 Deg were detd. Photochem. 1-7 shifts of hydrogen are also reported: the 1-isomer yields preferentially the 7-isomer and little of the 2-isomer, while the 2-isomer yields mainly the 3-isomer and little of the alternative 1-isomer. [on SciFinder (R)]",

author = "\{Borg, ter\}, A.P. and H. Kloosterziel",

year = "1969",

doi = "10.1002/recl.19690880303",

language = "English",

volume = "88",

pages = "266--274",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

issn = "0165-0513",

publisher = "Royal Netherlands Chemical Society",

number = "3",

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T1 - The chemistry of cycloheptatriene. Part XVI : Sigmatropic shifts of hydrogen in methylcycloheptatriene

AU - Borg, ter, A.P.

AU - Kloosterziel, H.

PY - 1969

Y1 - 1969

N2 - Upon heating 7-methylcycloheptatriene, the 3-, 1- and 2-isomers are successively formed by 1-5 shifts of hydrogen. The rate consts. at 140 Deg were detd. Photochem. 1-7 shifts of hydrogen are also reported: the 1-isomer yields preferentially the 7-isomer and little of the 2-isomer, while the 2-isomer yields mainly the 3-isomer and little of the alternative 1-isomer. [on SciFinder (R)]

AB - Upon heating 7-methylcycloheptatriene, the 3-, 1- and 2-isomers are successively formed by 1-5 shifts of hydrogen. The rate consts. at 140 Deg were detd. Photochem. 1-7 shifts of hydrogen are also reported: the 1-isomer yields preferentially the 7-isomer and little of the 2-isomer, while the 2-isomer yields mainly the 3-isomer and little of the alternative 1-isomer. [on SciFinder (R)]

U2 - 10.1002/recl.19690880303

DO - 10.1002/recl.19690880303

M3 - Article

SN - 0165-0513

VL - 88

SP - 266

EP - 274

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 3

ER -

The chemistry of cycloheptatriene. Part XVI : Sigmatropic shifts of hydrogen in methylcycloheptatriene

Abstract

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