The chemistry of cycloheptatriene, part XIV : Hydrogen shifts in (4-Dimethylaminophenyl)cycloheptatrienes

A.P. Borg, ter; H. Kloosterziel; Y.L. Westphal

doi:10.1002/recl.19670860502

The chemistry of cycloheptatriene, part XIV : Hydrogen shifts in (4-Dimethylaminophenyl)cycloheptatrienes

A.P. Borg, ter
, H. Kloosterziel
, Y.L. Westphal

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

12 Citations (Scopus)

Abstract

When the 7-isomer of the title compound is heated, the successive formation of the 3-, 1-, and 2-isomers by thermal 1–5 shifts of hydrogen is observed. Irradiation of the 3-isomer yields the 2-isomer. The rate constants for the various shifts are 1.7 ± 0.4 times larger than the corresponding constants for phenylcycloheptatriene.

Original language	English
Pages (from-to)	474-480
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	86
Issue number	5
DOIs	https://doi.org/10.1002/recl.19670860502
Publication status	Published - 1967

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title = "The chemistry of cycloheptatriene, part XIV : Hydrogen shifts in (4-Dimethylaminophenyl)cycloheptatrienes",

abstract = "When the 7-isomer of the title compound is heated, the successive formation of the 3-, 1-, and 2-isomers by thermal 1–5 shifts of hydrogen is observed. Irradiation of the 3-isomer yields the 2-isomer. The rate constants for the various shifts are 1.7 ± 0.4 times larger than the corresponding constants for phenylcycloheptatriene.",

author = "\{Borg, ter\}, A.P. and H. Kloosterziel and Y.L. Westphal",

year = "1967",

doi = "10.1002/recl.19670860502",

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pages = "474--480",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

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T1 - The chemistry of cycloheptatriene, part XIV : Hydrogen shifts in (4-Dimethylaminophenyl)cycloheptatrienes

AU - Borg, ter, A.P.

AU - Kloosterziel, H.

AU - Westphal, Y.L.

PY - 1967

Y1 - 1967

N2 - When the 7-isomer of the title compound is heated, the successive formation of the 3-, 1-, and 2-isomers by thermal 1–5 shifts of hydrogen is observed. Irradiation of the 3-isomer yields the 2-isomer. The rate constants for the various shifts are 1.7 ± 0.4 times larger than the corresponding constants for phenylcycloheptatriene.

AB - When the 7-isomer of the title compound is heated, the successive formation of the 3-, 1-, and 2-isomers by thermal 1–5 shifts of hydrogen is observed. Irradiation of the 3-isomer yields the 2-isomer. The rate constants for the various shifts are 1.7 ± 0.4 times larger than the corresponding constants for phenylcycloheptatriene.

U2 - 10.1002/recl.19670860502

DO - 10.1002/recl.19670860502

M3 - Article

SN - 0165-0513

VL - 86

SP - 474

EP - 480

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 5

ER -

The chemistry of cycloheptatriene, part XIV : Hydrogen shifts in (4-Dimethylaminophenyl)cycloheptatrienes

Abstract

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