Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

M.C.C. Janssen; L. Bini; B. Hamers; C. Müller; D. Hess; A. Christiansen; R. Franke; D. Vogt

doi:10.1016/j.tetlet.2010.02.035

Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

M.C.C. Janssen
, L. Bini
, B. Hamers
, C. Müller
, D. Hess
, A. Christiansen
, R. Franke
, D. Vogt

Research output: Contribution to journal › Article › Academic › peer-review

8 Citations (Scopus)

2 Downloads (Pure)

Abstract

A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1–TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.

Original language	English
Pages (from-to)	1971-1975
Number of pages	5
Journal	Tetrahedron Letters
Volume	51
Issue number	15
DOIs	https://doi.org/10.1016/j.tetlet.2010.02.035
Publication status	Published - 2010

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title = "Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes",

abstract = "A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1{\textendash}TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.",

author = "M.C.C. Janssen and L. Bini and B. Hamers and C. M{\"u}ller and D. Hess and A. Christiansen and R. Franke and D. Vogt",

year = "2010",

doi = "10.1016/j.tetlet.2010.02.035",

language = "English",

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pages = "1971--1975",

journal = "Tetrahedron Letters",

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T1 - Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

AU - Janssen, M.C.C.

AU - Bini, L.

AU - Hamers, B.

AU - Müller, C.

AU - Hess, D.

AU - Christiansen, A.

AU - Franke, R.

AU - Vogt, D.

PY - 2010

Y1 - 2010

N2 - A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1–TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.

AB - A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1–TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.

U2 - 10.1016/j.tetlet.2010.02.035

DO - 10.1016/j.tetlet.2010.02.035

M3 - Article

SN - 0040-4039

VL - 51

SP - 1971

EP - 1975

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

Abstract

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