Tetraphenol-based diphosphite ligands : synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

M.C.C. Janssen, L. Bini, B. Hamers, C. Müller, D. Hess, A. Christiansen, R. Franke, D. Vogt

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    Abstract

    A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1–TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.
    Original languageEnglish
    Pages (from-to)1971-1975
    Number of pages5
    JournalTetrahedron Letters
    Volume51
    Issue number15
    DOIs
    Publication statusPublished - 2010

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