Tetrachloro-substituted perylene bisimide dyes as promising n-type organic semiconductors : studies on structural, electrochemical and charge transport properties

Zhijian Chen, M.G. Debije, T. Dabaerdemaker, P. Osswald, F. Würthner

Research output: Contribution to journalArticleAcademicpeer-review

231 Citations (Scopus)

Abstract

Twisted p-systems: The highly twisted 1,6,7,12-tetrachloro-substituted perylene bisimides possess an improved electron affinity. The nonplanar nature of these molecules facilitates a slipped brickstone-type rather than a columnar stacking of the p-systems, with a potentially useful two dimensional contact feature. These compounds show isotropic charge carrier mobilities as high as up to 0.14 cm2¿V-1 s-1 (see graphic).
LanguageEnglish
Pages137-140
JournalChemPhysChem
Volume5
Issue number1
DOIs
StatePublished - 2004

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Electron affinity
n-type semiconductors
Semiconducting organic compounds
Carrier mobility
organic semiconductors
carrier mobility
electron affinity
Charge carriers
Transport properties
Charge transfer
charge carriers
Coloring Agents
transport properties
dyes
Molecules
molecules
perylene bisimide

Cite this

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Tetrachloro-substituted perylene bisimide dyes as promising n-type organic semiconductors : studies on structural, electrochemical and charge transport properties. / Chen, Zhijian; Debije, M.G.; Dabaerdemaker, T.; Osswald, P.; Würthner, F.

In: ChemPhysChem, Vol. 5, No. 1, 2004, p. 137-140.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Tetrachloro-substituted perylene bisimide dyes as promising n-type organic semiconductors : studies on structural, electrochemical and charge transport properties

AU - Chen,Zhijian

AU - Debije,M.G.

AU - Dabaerdemaker,T.

AU - Osswald,P.

AU - Würthner,F.

PY - 2004

Y1 - 2004

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AB - Twisted p-systems: The highly twisted 1,6,7,12-tetrachloro-substituted perylene bisimides possess an improved electron affinity. The nonplanar nature of these molecules facilitates a slipped brickstone-type rather than a columnar stacking of the p-systems, with a potentially useful two dimensional contact feature. These compounds show isotropic charge carrier mobilities as high as up to 0.14 cm2¿V-1 s-1 (see graphic).

U2 - 10.1002/cphc.200300882

DO - 10.1002/cphc.200300882

M3 - Article

VL - 5

SP - 137

EP - 140

JO - ChemPhysChem

T2 - ChemPhysChem

JF - ChemPhysChem

SN - 1439-4235

IS - 1

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