Templated assembly of a molecular capsule

J.N.H. Reek, A.P.H.J. Schenning, A.W. Bosman, E.W. Meijer, M.J. Crossley

Research output: Contribution to journalArticleAcademicpeer-review

81 Citations (Scopus)

Abstract

Two rigid Troger's base dizinc(II) bis-porphyrin receptor mols. (I) and the 1st generation of dendrimer tetramine N,N,N',N'-Tetrakis(3-aminopropyl)-1,4-diaminobutane (4) form a 2:1 complex 5, a self-assembled spherical superstructure encapsulating the dendrimer. UV-vis binding studies of I with 1,7-diaminoheptane (2) and 1,12-diaminododecane (3) indicate that the 14 atom chain binds more strongly than the 9 atom chain which is consistent with the proposed structure of 5
Original languageEnglish
Pages (from-to)11-12
JournalChemical Communications
Volume1998
Issue number1
DOIs
Publication statusPublished - 1998

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