Templated assembly of a molecular capsule

J.N.H. Reek; A.P.H.J. Schenning; A.W. Bosman; E.W. Meijer; M.J. Crossley

doi:10.1039/a707748c

Templated assembly of a molecular capsule

J.N.H. Reek, A.P.H.J. Schenning, A.W. Bosman, E.W. Meijer, M.J. Crossley

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Abstract

Two rigid Troger's base dizinc(II) bis-porphyrin receptor mols. (I) and the 1st generation of dendrimer tetramine N,N,N',N'-Tetrakis(3-aminopropyl)-1,4-diaminobutane (4) form a 2:1 complex 5, a self-assembled spherical superstructure encapsulating the dendrimer. UV-vis binding studies of I with 1,7-diaminoheptane (2) and 1,12-diaminododecane (3) indicate that the 14 atom chain binds more strongly than the 9 atom chain which is consistent with the proposed structure of 5

Original language	English
Pages (from-to)	11-12
Journal	Chemical Communications, ChemComm
Volume	1998
Issue number	1
DOIs	https://doi.org/10.1039/a707748c
Publication status	Published - 1998

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T1 - Templated assembly of a molecular capsule

AU - Reek, J.N.H.

AU - Schenning, A.P.H.J.

AU - Bosman, A.W.

AU - Meijer, E.W.

AU - Crossley, M.J.

PY - 1998

Y1 - 1998

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AB - Two rigid Troger's base dizinc(II) bis-porphyrin receptor mols. (I) and the 1st generation of dendrimer tetramine N,N,N',N'-Tetrakis(3-aminopropyl)-1,4-diaminobutane (4) form a 2:1 complex 5, a self-assembled spherical superstructure encapsulating the dendrimer. UV-vis binding studies of I with 1,7-diaminoheptane (2) and 1,12-diaminododecane (3) indicate that the 14 atom chain binds more strongly than the 9 atom chain which is consistent with the proposed structure of 5

U2 - 10.1039/a707748c

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M3 - Article

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VL - 1998

SP - 11

EP - 12

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

IS - 1

ER -

Templated assembly of a molecular capsule

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