T-Shaped Cationic Cu(I) Complexes with Hemilabile PNP-Type Ligands

J.I. Vlugt, van der; E.A. Pidko; D. Vogt; M. Lutz; A.L. Spek; A. Meetsma

doi:10.1021/ic800298a

T-Shaped Cationic Cu(I) Complexes with Hemilabile PNP-Type Ligands

J.I. Vlugt, van der, E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek, A. Meetsma

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

71 Citations (Scopus)

Abstract

The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center

Original language	English
Pages (from-to)	4442-4444
Journal	Inorganic Chemistry
Volume	47
Issue number	11
DOIs	https://doi.org/10.1021/ic800298a
Publication status	Published - 2008

Access to Document

10.1021/ic800298a

Cite this

@article{9fabcd2aa0d941f095da6b093cf5ea9a,

title = "T-Shaped Cationic Cu(I) Complexes with Hemilabile PNP-Type Ligands",

abstract = "The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center",

author = "{Vlugt, van der}, J.I. and E.A. Pidko and D. Vogt and M. Lutz and A.L. Spek and A. Meetsma",

year = "2008",

doi = "10.1021/ic800298a",

language = "English",

volume = "47",

pages = "4442--4444",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - T-Shaped Cationic Cu(I) Complexes with Hemilabile PNP-Type Ligands

AU - Vlugt, van der, J.I.

AU - Pidko, E.A.

AU - Vogt, D.

AU - Lutz, M.

AU - Spek, A.L.

AU - Meetsma, A.

PY - 2008

Y1 - 2008

N2 - The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center

AB - The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center

U2 - 10.1021/ic800298a

DO - 10.1021/ic800298a

M3 - Article

C2 - 18442230

SN - 0020-1669

VL - 47

SP - 4442

EP - 4444

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

T-Shaped Cationic Cu(I) Complexes with Hemilabile PNP-Type Ligands

Abstract

Access to Document

Fingerprint

Cite this