Synthesis, optimization and application of tailor-made ionic liquids for heterogeneous polymerization processes

C.A. Guerrero-Sanchez, T. Erdmenger, F.D. Wiesbrock, U.S. Schubert

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

Abstract

Different water-sol. 3-methyl-imidazolium chloride based ionic liqs. contg. side groups of different aliph. chain lengths have been prepd. via microwave-assisted synthesis. Reaction conditions for this synthetic approach have been optimized as well. The obtained ionic liqs. and their aq. solns. were used to perform and stabilize dispersion polymns. of cross-linked polymeric beads (which can find application in anal. purposes such as chromatog. columns). The aliph. chain length as well as the concn. of the ionic liqs. in the aq. solns. revealed an important influence on the stabilization of dispersions, allowing to \"tune\" the size of the synthesized beads from millimeter scale to nanometer scale. Moreover, the ionic liqs. and/or their aq. solns. could be recovered after the synthesis of the beads and used again as a reaction medium for performing new reactions opening an \"environmentally friendly\" approach to this synthetic procedure. [on SciFinder (R)]
Original languageEnglish
Title of host publicationAbstracts of Papers, 231st ACS National Meeting, Atlanta, GA, United States, March 26-30, 2006
PagesIEC-303
Publication statusPublished - 2006

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