Synthesis of well-defined perfluoroalkyl-end-capped polymers by ring-opening polymerization

T. Dikic; W. Ming; R.A.T.M. Benthem, van; G. With, de

Synthesis of well-defined perfluoroalkyl-end-capped polymers by ring-opening polymerization

T. Dikic, W. Ming, R.A.T.M. Benthem, van, G. With, de

Materials and Interface Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

Abstract

For the purpose of developing model coating systems, it is important to use well-defined coating precursors. In this work, perfluoroalkyl-end-capped polyesters were synthesized by ring-opening polymerization of e-caprolactone (e-Cl) through so-called 'activated monomer' mechanism. The polymerization of e-Cl in a living manner, making the molecular weight of polycaprolactone easily tunable, with a low polydispersity index (~1.1). In addition, no cyclic structures have been observed.

Original language	English
Title of host publication	International Conference on Fluorine and Silicone Coatings
Place of Publication	United Kingdom, Manchester
Pages	Paper-3
Publication status	Published - 2005

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@inproceedings{3565edbe18914f8ca2deff8761946c48,

title = "Synthesis of well-defined perfluoroalkyl-end-capped polymers by ring-opening polymerization",

abstract = "For the purpose of developing model coating systems, it is important to use well-defined coating precursors. In this work, perfluoroalkyl-end-capped polyesters were synthesized by ring-opening polymerization of e-caprolactone (e-Cl) through so-called 'activated monomer' mechanism. The polymerization of e-Cl in a living manner, making the molecular weight of polycaprolactone easily tunable, with a low polydispersity index (~1.1). In addition, no cyclic structures have been observed.",

author = "T. Dikic and W. Ming and {Benthem, van}, R.A.T.M. and {With, de}, G.",

year = "2005",

language = "English",

pages = "Paper--3",

booktitle = "International Conference on Fluorine and Silicone Coatings",

}

TY - GEN

T1 - Synthesis of well-defined perfluoroalkyl-end-capped polymers by ring-opening polymerization

AU - Dikic, T.

AU - Ming, W.

AU - Benthem, van, R.A.T.M.

AU - With, de, G.

PY - 2005

Y1 - 2005

N2 - For the purpose of developing model coating systems, it is important to use well-defined coating precursors. In this work, perfluoroalkyl-end-capped polyesters were synthesized by ring-opening polymerization of e-caprolactone (e-Cl) through so-called 'activated monomer' mechanism. The polymerization of e-Cl in a living manner, making the molecular weight of polycaprolactone easily tunable, with a low polydispersity index (~1.1). In addition, no cyclic structures have been observed.

AB - For the purpose of developing model coating systems, it is important to use well-defined coating precursors. In this work, perfluoroalkyl-end-capped polyesters were synthesized by ring-opening polymerization of e-caprolactone (e-Cl) through so-called 'activated monomer' mechanism. The polymerization of e-Cl in a living manner, making the molecular weight of polycaprolactone easily tunable, with a low polydispersity index (~1.1). In addition, no cyclic structures have been observed.

M3 - Conference contribution

SP - Paper-3

BT - International Conference on Fluorine and Silicone Coatings

CY - United Kingdom, Manchester

ER -

Synthesis of well-defined perfluoroalkyl-end-capped polymers by ring-opening polymerization

Abstract

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