Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture

S.A. Kuznetsov; S.V. Kuznetsova; E.V. Rebrov; M.J.M. Mies; M.H.J.M. Croon, de; J.C. Schouten

doi:10.1016/j.surfcoat.2004.05.021

Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture

S.A. Kuznetsov
, S.V. Kuznetsova
, E.V. Rebrov
, M.J.M. Mies
, M.H.J.M. Croon, de
, J.C. Schouten

Chemical Reactor Engineering

Research output: Contribution to journal › Article › Academic › peer-review

38 Citations (Scopus)

Abstract

The formation of various coatings in molybdenum-boron and molybdenum-silicon systems was investigated. Boronizing and siliciding treatments were conducted in molten salts under inert gas atm. in the 850-1050 DegC temp. range for 7 h. The presence of boride (e.g. Mo2B, MoB, Mo2B5) and silicide (MoSi2, Mo5Si3) phases, formed on the surface of Mo plates, was confirmed by X-ray diffraction anal. The distribution of elements was detd. by means of wavelength dispersive spectroscopy (WDS) spectra of the surface and line-scan analyses from surface to interior. Depending on the process type (diffusional or electrochem.) and temp., the thickness of the protective layers formed on the substrate ranged from 6 to 40 mm. The oxidn. resistance of obtained phases was investigated in an air-water mixt. in the temp. range of 500-700 DegC for a period up to 400 h. An improved oxidn. behavior of coated plates in comparison with that of pure molybdenum was obsd. [on SciFinder (R)]

Original language	English
Pages (from-to)	182-188
Number of pages	7
Journal	Surface and Coatings Technology
Volume	195
Issue number	2-3
DOIs	https://doi.org/10.1016/j.surfcoat.2004.05.021
Publication status	Published - 2005

Access to Document

10.1016/j.surfcoat.2004.05.021

Cite this

@article{9efbda0b0f664aea88b76a36aeba4489,

title = "Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture",

abstract = "The formation of various coatings in molybdenum-boron and molybdenum-silicon systems was investigated. Boronizing and siliciding treatments were conducted in molten salts under inert gas atm. in the 850-1050 DegC temp. range for 7 h. The presence of boride (e.g. Mo2B, MoB, Mo2B5) and silicide (MoSi2, Mo5Si3) phases, formed on the surface of Mo plates, was confirmed by X-ray diffraction anal. The distribution of elements was detd. by means of wavelength dispersive spectroscopy (WDS) spectra of the surface and line-scan analyses from surface to interior. Depending on the process type (diffusional or electrochem.) and temp., the thickness of the protective layers formed on the substrate ranged from 6 to 40 mm. The oxidn. resistance of obtained phases was investigated in an air-water mixt. in the temp. range of 500-700 DegC for a period up to 400 h. An improved oxidn. behavior of coated plates in comparison with that of pure molybdenum was obsd. [on SciFinder (R)]",

author = "S.A. Kuznetsov and S.V. Kuznetsova and E.V. Rebrov and M.J.M. Mies and \{Croon, de\}, M.H.J.M. and J.C. Schouten",

year = "2005",

doi = "10.1016/j.surfcoat.2004.05.021",

language = "English",

volume = "195",

pages = "182--188",

journal = "Surface and Coatings Technology",

issn = "0257-8972",

publisher = "Elsevier B.V.",

number = "2-3",

}

TY - JOUR

T1 - Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture

AU - Kuznetsov, S.A.

AU - Kuznetsova, S.V.

AU - Rebrov, E.V.

AU - Mies, M.J.M.

AU - Croon, de, M.H.J.M.

AU - Schouten, J.C.

PY - 2005

Y1 - 2005

N2 - The formation of various coatings in molybdenum-boron and molybdenum-silicon systems was investigated. Boronizing and siliciding treatments were conducted in molten salts under inert gas atm. in the 850-1050 DegC temp. range for 7 h. The presence of boride (e.g. Mo2B, MoB, Mo2B5) and silicide (MoSi2, Mo5Si3) phases, formed on the surface of Mo plates, was confirmed by X-ray diffraction anal. The distribution of elements was detd. by means of wavelength dispersive spectroscopy (WDS) spectra of the surface and line-scan analyses from surface to interior. Depending on the process type (diffusional or electrochem.) and temp., the thickness of the protective layers formed on the substrate ranged from 6 to 40 mm. The oxidn. resistance of obtained phases was investigated in an air-water mixt. in the temp. range of 500-700 DegC for a period up to 400 h. An improved oxidn. behavior of coated plates in comparison with that of pure molybdenum was obsd. [on SciFinder (R)]

AB - The formation of various coatings in molybdenum-boron and molybdenum-silicon systems was investigated. Boronizing and siliciding treatments were conducted in molten salts under inert gas atm. in the 850-1050 DegC temp. range for 7 h. The presence of boride (e.g. Mo2B, MoB, Mo2B5) and silicide (MoSi2, Mo5Si3) phases, formed on the surface of Mo plates, was confirmed by X-ray diffraction anal. The distribution of elements was detd. by means of wavelength dispersive spectroscopy (WDS) spectra of the surface and line-scan analyses from surface to interior. Depending on the process type (diffusional or electrochem.) and temp., the thickness of the protective layers formed on the substrate ranged from 6 to 40 mm. The oxidn. resistance of obtained phases was investigated in an air-water mixt. in the temp. range of 500-700 DegC for a period up to 400 h. An improved oxidn. behavior of coated plates in comparison with that of pure molybdenum was obsd. [on SciFinder (R)]

U2 - 10.1016/j.surfcoat.2004.05.021

DO - 10.1016/j.surfcoat.2004.05.021

M3 - Article

SN - 0257-8972

VL - 195

SP - 182

EP - 188

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

IS - 2-3

ER -

Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture

Abstract

Access to Document

Fingerprint

Cite this